Distribution and removal of fluorescent dissolved organic matter in 15 municipal wastewater treatment plants in China

Fluorescent dissolved organic matter (FDOM), having complex structures like aromatic structure and double bond structure, is able to represent relatively refractory parts of dissolved organic matter (DOM). This study investigated the distribution of FDOM in the influents and the removal in the secondary effluents of 15 municipal wastewater treatment plants (WWTPs) in 15 provincial capitals of China. Eight components have been identified using excitation emission matrix combined with parallel factor analysis (EEM-PARAFAC). Tryptophan-like (C1 or C4), terrestrial humic-like (C2) and microbial humic-like (C3) fluorescent components were major FDOM components in municipal wastewater, appearing in 11 WWTPs simultaneously. The removal of total fluorescence was generally about 30%–40%, while hydrophobic humic-like compounds (C5 and C8) were the most refractory components with 4%–16% removal and C3 was the second most refractory with −11%–41% removal. The compositions of FDOM in municipal wastewater were different in northeast/west and middle/east regions according to the self-organized map (SOM) analysis. Wastewater sources had more important influence on fluorescent characteristics of secondary effluents than biological treatment processes. Besides, this study found that humification index (HIX) was the most suitable index to describe the bulk fluorescent character of wastewater since it had a good correlation with abundance, removal and ratios of main fluorescent components either in the influents or in the secondary effluents.