Direct oxidation of the C(sp2)-C(sp3) bond from benzyltrimethylsilanes to phenols

Wei Li; Guolin Gao; Yuan Gao; Chao Yang; Wujiong Xia

doi:10.1039/c7cc01868a

Direct oxidation of the C(sp²)-C(sp³) bond from benzyltrimethylsilanes to phenols

Wei Li
, Guolin Gao
, Yuan Gao
, Chao Yang^*
, Wujiong Xia

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Harbin University of Commerce
Yantai University

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A novel pathway for direct conversion of benzylsilanes to phenols by oxidation with Na₂S₂O₈ and oxygen is efficiently developed under mild and neutral conditions. The reaction shows good functional group tolerance to afford phenols in moderate yields. The possible mechanism is proposed based on the isotopic labeling trials.

Original language	English
Pages (from-to)	5291-5293
Number of pages	3
Journal	Chemical Communications
Volume	53
Issue number	38
DOIs	https://doi.org/10.1039/c7cc01868a
State	Published - 2017
Externally published	Yes

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10.1039/c7cc01868a

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title = "Direct oxidation of the C(sp2)-C(sp3) bond from benzyltrimethylsilanes to phenols",

abstract = "A novel pathway for direct conversion of benzylsilanes to phenols by oxidation with Na2S2O8 and oxygen is efficiently developed under mild and neutral conditions. The reaction shows good functional group tolerance to afford phenols in moderate yields. The possible mechanism is proposed based on the isotopic labeling trials.",

author = "Wei Li and Guolin Gao and Yuan Gao and Chao Yang and Wujiong Xia",

note = "Publisher Copyright: {\textcopyright} 2017 The Royal Society of Chemistry.",

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doi = "10.1039/c7cc01868a",

language = "英语",

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T1 - Direct oxidation of the C(sp2)-C(sp3) bond from benzyltrimethylsilanes to phenols

AU - Li, Wei

AU - Gao, Guolin

AU - Gao, Yuan

AU - Yang, Chao

AU - Xia, Wujiong

PY - 2017

Y1 - 2017

N2 - A novel pathway for direct conversion of benzylsilanes to phenols by oxidation with Na2S2O8 and oxygen is efficiently developed under mild and neutral conditions. The reaction shows good functional group tolerance to afford phenols in moderate yields. The possible mechanism is proposed based on the isotopic labeling trials.

AB - A novel pathway for direct conversion of benzylsilanes to phenols by oxidation with Na2S2O8 and oxygen is efficiently developed under mild and neutral conditions. The reaction shows good functional group tolerance to afford phenols in moderate yields. The possible mechanism is proposed based on the isotopic labeling trials.

UR - https://www.scopus.com/pages/publications/85021664849

U2 - 10.1039/c7cc01868a

DO - 10.1039/c7cc01868a

M3 - 文章

C2 - 28443927

AN - SCOPUS:85021664849

SN - 1359-7345

VL - 53

SP - 5291

EP - 5293

JO - Chemical Communications

JF - Chemical Communications

IS - 38

ER -

Direct oxidation of the C(sp²)-C(sp³) bond from benzyltrimethylsilanes to phenols

Abstract

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