Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

Dan Zhu; Denghu Chang; Shaoyan Gan; Lei Shi

doi:10.1039/c6ra01799a

Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

Dan Zhu
, Denghu Chang
, Shaoyan Gan
, Lei Shi^*

^*Corresponding author for this work

School of Sciences

Harbin Institute of Technology Shenzhen
Harbin Institute of Technology
Nankai University

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

A novel metal-free approach to directly synthesize α-acyloxy sulfides from readily available alkyl sulfides utilizing the hypervalent (diacyloxyiodo)benzene and TBAB reagent combination is reported. This transformation is characterized by its broad substrate scope in moderate to excellent yields, convenient operating conditions and outstanding functional group tolerance.

Original language	English
Pages (from-to)	27983-27987
Number of pages	5
Journal	RSC Advances
Volume	6
Issue number	33
DOIs	https://doi.org/10.1039/c6ra01799a
State	Published - 2016

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title = "Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination",

abstract = "A novel metal-free approach to directly synthesize α-acyloxy sulfides from readily available alkyl sulfides utilizing the hypervalent (diacyloxyiodo)benzene and TBAB reagent combination is reported. This transformation is characterized by its broad substrate scope in moderate to excellent yields, convenient operating conditions and outstanding functional group tolerance.",

author = "Dan Zhu and Denghu Chang and Shaoyan Gan and Lei Shi",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",

year = "2016",

doi = "10.1039/c6ra01799a",

language = "英语",

volume = "6",

pages = "27983--27987",

journal = "RSC Advances",

issn = "2046-2069",

publisher = "Royal Society of Chemistry",

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T1 - Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

AU - Zhu, Dan

AU - Chang, Denghu

AU - Gan, Shaoyan

AU - Shi, Lei

PY - 2016

Y1 - 2016

N2 - A novel metal-free approach to directly synthesize α-acyloxy sulfides from readily available alkyl sulfides utilizing the hypervalent (diacyloxyiodo)benzene and TBAB reagent combination is reported. This transformation is characterized by its broad substrate scope in moderate to excellent yields, convenient operating conditions and outstanding functional group tolerance.

AB - A novel metal-free approach to directly synthesize α-acyloxy sulfides from readily available alkyl sulfides utilizing the hypervalent (diacyloxyiodo)benzene and TBAB reagent combination is reported. This transformation is characterized by its broad substrate scope in moderate to excellent yields, convenient operating conditions and outstanding functional group tolerance.

UR - https://www.scopus.com/pages/publications/84961658131

U2 - 10.1039/c6ra01799a

DO - 10.1039/c6ra01799a

M3 - 文章

AN - SCOPUS:84961658131

SN - 2046-2069

VL - 6

SP - 27983

EP - 27987

JO - RSC Advances

JF - RSC Advances

IS - 33

ER -

Direct α-acyloxylation of organic sulfides with the hypervalent (diacyloxyiodo)benzene/tetra-n-butylammonium bromide (TBAB) reagent combination

Abstract

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