Diamond-Like Carbon Films for Electrochemical Sensor

A. Zeng; E. Liu; S. Zhang; S. N. Tan; L. X. Liu; J. Gao

doi:10.4028/www.scientific.net/msf.437-438.467

Diamond-Like Carbon Films for Electrochemical Sensor

A. Zeng^*
, E. Liu
, S. Zhang
, S. N. Tan
, L. X. Liu
, J. Gao

^*Corresponding author for this work

Nanyang Technological University

Research output: Contribution to journal › Conference article › peer-review

3 Scopus citations

Abstract

In this paper, conductive nitrogen doped diamond-like carbon (N-DLC) films were deposited with dc magnetron sputtering, and their performance in acids as well as application as working electrodes for lead stripping analysis had been studied. It was found that N-DLC film has a double-layer capacitance about 3.45 μF·cm^-2 in 0.5 M H₂SO₄, a wide potential window in acids, and a high catalytic activity for Cl ₂/Cl^-. The N-DLC electrodes also had a high signal of Pb²⁺/Pb⁰, and their stripping detection limit without mercury coating was about 76 nM in 0.1 M KCl (pH1) solution. Their double layer capacitance, width of potential window, and stripping detection limit are comparable with that of boron doped diamond film electrodes. N-DLC film has shown to be a suitable work electrode material for electrochemical sensors.

Original language	English
Pages (from-to)	467-470
Number of pages	4
Journal	Materials Science Forum
Volume	437-438
DOIs	https://doi.org/10.4028/www.scientific.net/msf.437-438.467
State	Published - 2003
Externally published	Yes
Event	Proceedings of the 2nd International Conference on Advanced Materials Processing - Singapore, Singapore Duration: 2 Dec 2002 → 4 Dec 2002

Keywords

Diamond-Like Carbon Film
Electrochemical Characteristics
Electrode
Nitrogen Doping

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Cite this

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title = "Diamond-Like Carbon Films for Electrochemical Sensor",

abstract = "In this paper, conductive nitrogen doped diamond-like carbon (N-DLC) films were deposited with dc magnetron sputtering, and their performance in acids as well as application as working electrodes for lead stripping analysis had been studied. It was found that N-DLC film has a double-layer capacitance about 3.45 μF·cm-2 in 0.5 M H2SO4, a wide potential window in acids, and a high catalytic activity for Cl 2/Cl-. The N-DLC electrodes also had a high signal of Pb2+/Pb0, and their stripping detection limit without mercury coating was about 76 nM in 0.1 M KCl (pH1) solution. Their double layer capacitance, width of potential window, and stripping detection limit are comparable with that of boron doped diamond film electrodes. N-DLC film has shown to be a suitable work electrode material for electrochemical sensors.",

keywords = "Diamond-Like Carbon Film, Electrochemical Characteristics, Electrode, Nitrogen Doping",

author = "A. Zeng and E. Liu and S. Zhang and Tan, \{S. N.\} and Liu, \{L. X.\} and J. Gao",

year = "2003",

doi = "10.4028/www.scientific.net/msf.437-438.467",

language = "英语",

volume = "437-438",

pages = "467--470",

journal = "Materials Science Forum",

issn = "0255-5476",

publisher = "Trans Tech Publications Ltd",

note = "Proceedings of the 2nd International Conference on Advanced Materials Processing ; Conference date: 02-12-2002 Through 04-12-2002",

}

TY - JOUR

T1 - Diamond-Like Carbon Films for Electrochemical Sensor

AU - Zeng, A.

AU - Liu, E.

AU - Zhang, S.

AU - Tan, S. N.

AU - Liu, L. X.

AU - Gao, J.

PY - 2003

Y1 - 2003

N2 - In this paper, conductive nitrogen doped diamond-like carbon (N-DLC) films were deposited with dc magnetron sputtering, and their performance in acids as well as application as working electrodes for lead stripping analysis had been studied. It was found that N-DLC film has a double-layer capacitance about 3.45 μF·cm-2 in 0.5 M H2SO4, a wide potential window in acids, and a high catalytic activity for Cl 2/Cl-. The N-DLC electrodes also had a high signal of Pb2+/Pb0, and their stripping detection limit without mercury coating was about 76 nM in 0.1 M KCl (pH1) solution. Their double layer capacitance, width of potential window, and stripping detection limit are comparable with that of boron doped diamond film electrodes. N-DLC film has shown to be a suitable work electrode material for electrochemical sensors.

AB - In this paper, conductive nitrogen doped diamond-like carbon (N-DLC) films were deposited with dc magnetron sputtering, and their performance in acids as well as application as working electrodes for lead stripping analysis had been studied. It was found that N-DLC film has a double-layer capacitance about 3.45 μF·cm-2 in 0.5 M H2SO4, a wide potential window in acids, and a high catalytic activity for Cl 2/Cl-. The N-DLC electrodes also had a high signal of Pb2+/Pb0, and their stripping detection limit without mercury coating was about 76 nM in 0.1 M KCl (pH1) solution. Their double layer capacitance, width of potential window, and stripping detection limit are comparable with that of boron doped diamond film electrodes. N-DLC film has shown to be a suitable work electrode material for electrochemical sensors.

KW - Diamond-Like Carbon Film

KW - Electrochemical Characteristics

KW - Electrode

KW - Nitrogen Doping

UR - https://www.scopus.com/pages/publications/0242305123

U2 - 10.4028/www.scientific.net/msf.437-438.467

DO - 10.4028/www.scientific.net/msf.437-438.467

M3 - 会议文章

AN - SCOPUS:0242305123

SN - 0255-5476

VL - 437-438

SP - 467

EP - 470

JO - Materials Science Forum

JF - Materials Science Forum

T2 - Proceedings of the 2nd International Conference on Advanced Materials Processing

Y2 - 2 December 2002 through 4 December 2002

ER -

Diamond-Like Carbon Films for Electrochemical Sensor

Abstract

Keywords

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