Dewatering efficiency of sewage sludge during Fe²⁺-activated persulfate oxidation: Effect of hydrophobic/hydrophilic properties of sludge EPS

To clarify the effect of the hydrophobic/hydrophilic polarity of extracellular polymeric substances (EPS) on sludge filterability improvement during S₂O₈^2-/Fe²⁺ oxidation, waste activated sludge (WAS), glucose-fed hydrophilic sludge (HPI-WAS), and sodium acetate-fed hydrophobic sludge (HPO-WAS) samples were cultivated, and their dewatering behaviors were individually explored. Experimental results showed that S₂O₈^2- oxidation effectively disintegrated the polymeric EPS and led to a more significant reduction in the water content for HPO-WAS than for HPI-WAS (12.87–15.23% vs 9.31–12.12%), especially regarding the bound water (W_b) content. After oxidation, as high as 38.88–42.61% of the W_b within HPO-WAS samples were declined, much higher than the HPI-WAS samples (19.27–29.20%). Specifically, carbohydrates within sludge EPS negatively influenced the dewatering process of S₂O₈^2-/Fe²⁺ oxidation. By contrast, abundant existence of humic acids and polymeric proteinaceous components (especially those hydrophilic proteins and transitional humic acids) within the sludge EPS exhibited a converse trend. FT-IR and EEM spectral, as well as particle sizes variation for the sludge samples before and after S₂O₈^2-/Fe²⁺ oxidation was also evaluated. This study provides new insight into the enhancement of S₂O₈^2-/Fe²⁺ oxidation for sludge dewatering based on polarity analysis of EPS.