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Degradable behavior and bioactivity of micro-arc oxidized AZ91D Mg alloy with calcium phosphate/chitosan composite coating in m-SBF

  • Jie Zhang
  • , Changsong Dai*
  • , Jie Wei
  • , Zhaohui Wen
  • , Shujuan Zhang
  • , Chuang Chen
  • *Corresponding author for this work
  • School of Chemistry and Chemical Engineering, Harbin Institute of Technology
  • Jiamusi University
  • Suzhou University of Science and Technology
  • The First Affiliated Hospital of Harbin Medical University

Research output: Contribution to journalArticlepeer-review

Abstract

The degradation behavior of a MAO-AZ91D with a calcium phosphate/chitosan composite coating in the modified simulated human body fluid (m-SBF) was investigated by immersion experiments and electrochemical impedance spectroscopy. The compositions of the composite coating soaked in the m-SBF for different time intervals were studied by X-ray diffraction, Fourier transform infrared spectroscopy, Raman spectroscopy, thermo-gravimetric analysis and differential thermal analysis. The microstructures of the composite coating at different soaking stages were observed by using a scanning electron microscope. Results show that the as-prepared composite coating could slow down the corrosion rate of the AZ91D alloy and it demonstrated good bioactivity in the m-SBF. The coating's morphology changed from a flake-like one into a spherical-shaped one with the increase of immersion time in the m-SBF.

Original languageEnglish
Pages (from-to)179-187
Number of pages9
JournalColloids and Surfaces B: Biointerfaces
Volume111
DOIs
StatePublished - 1 Nov 2013
Externally publishedYes

Keywords

  • Bioactivity
  • Calcium phosphate coating
  • Chitosan
  • Degradable behavior
  • Mg alloy

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