CuFe₂O₄/diatomite actuates peroxymonosulfate activation process: Mechanism for active species transformation and pesticide degradation

Peroxymonosulfate (PMS) activation is a promising technology for water purification, but the removal performance of multiple pollutant matrices and the mechanism for reactive species transformation in the heterogeneous catalytic system remain ambiguous. Herein, a novel CuFe₂O₄/diatomite was fabricated for PMS activation to achieve efficient removal of typical pesticides. Uniform distribution of CuFe₂O₄ on diatomite efficiently alleviated the agglomeration of CuFe₂O₄ and increased specific surface area (57.20 m² g⁻¹, 3.8-fold larger than CuFe₂O₄). CuFe₂O₄/5% diatomite (5-CFD)/PMS system showed nearly 100% removal efficiency for mixed pesticide solution within 10 min (0.10 g L⁻¹ 5-CFD and 0.40 g L⁻¹ PMS) and excellent anti-interference performance towards various coexisting substances (≥90% removal efficiency). The electrochemical measurements confirmed that the lower charge transfer resistance of 5-CFD significantly enhanced the electron-transfer capacity between 5-CFD and PMS, accelerating the reactions among [tbnd]Fe(III)/[tbnd]Fe(II), [tbnd]Cu(II)/[tbnd]Cu(I), and PMS, further generating •OH (261.3 μM), ¹O₂ (138.8 μM), SO₄^•– (11.8 μM), and O₂^•–. The O in reactive oxygen species didn't originate from dissolved oxygen (DO) but PMS, independent of the low solubility of DO and slow diffusion rate of O₂ in water. Furthermore, the production of ¹O₂ went through the process: PMS → O₂^•– → ¹O₂, and SO₄^•– could rapidly convert into •OH. The degradation pathways and the evolution of intermediates were proposed by HPLC-QTOF-MS/MS and DFT calculations. QSAR analysis illustrated that the toxicity became lower with the reaction process. This study provides novel insights into the mechanism for pesticide degradation and active species transformation and the anti-interference capability of systems.