Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4(μ2-OH)3} building block based metal organic framework through a dinuclear complex

Xin Ming Wang; Rui Qing Fan; Liang Sheng Qiang; Ping Wang; Yu Lin Yang; Yu Lei Wang

doi:10.1039/c4dt02045f

Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In₄(μ₂-OH)₃} building block based metal organic framework through a dinuclear complex

Xin Ming Wang
, Rui Qing Fan^*
, Liang Sheng Qiang
, Ping Wang
, Yu Lin Yang
, Yu Lei Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

A rare 3D tetranuclear {In₄(μ₂-OH)₃} building block based MOF {[In_4/3(μ₂-OH)(2,6-pydc)(1,4-bda)_0.5(H₂O)]·2H₂O}_n (2) was obtained through a crystal transformation from a dimeric complex In₃(2,6-pydc)₃(1,4-bda)_1.5(H₂O)₆ (1). With a 2D + 3D → 3D compact structure, 2 retains crystallinity in boiling water and organic solvents, exhibiting exceptional fluorescence quenching behaviour for the DMSO molecule.

Original language	English
Pages (from-to)	16152-16155
Number of pages	4
Journal	Dalton Transactions
Volume	43
Issue number	43
DOIs	https://doi.org/10.1039/c4dt02045f
State	Published - 21 Nov 2014

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10.1039/c4dt02045f

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@article{c88962b08d4645fca4d7d15cdae0f756,

title = "Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear \{In4(μ2-OH)3\} building block based metal organic framework through a dinuclear complex",

abstract = "A rare 3D tetranuclear \{In4(μ2-OH)3\} building block based MOF \{[In4/3(μ2-OH)(2,6-pydc)(1,4-bda)0.5(H2O)]·2H2O\}n (2) was obtained through a crystal transformation from a dimeric complex In3(2,6-pydc)3(1,4-bda)1.5(H2O)6 (1). With a 2D + 3D → 3D compact structure, 2 retains crystallinity in boiling water and organic solvents, exhibiting exceptional fluorescence quenching behaviour for the DMSO molecule.",

author = "Wang, \{Xin Ming\} and Fan, \{Rui Qing\} and Qiang, \{Liang Sheng\} and Ping Wang and Yang, \{Yu Lin\} and Wang, \{Yu Lei\}",

note = "Publisher Copyright: {\textcopyright} 2014 the Partner Organisations.",

year = "2014",

month = nov,

day = "21",

doi = "10.1039/c4dt02045f",

language = "英语",

volume = "43",

pages = "16152--16155",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

number = "43",

}

Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In₄(μ₂-OH)₃} building block based metal organic framework through a dinuclear complex. / Wang, Xin Ming; Fan, Rui Qing; Qiang, Liang Sheng et al.
In: Dalton Transactions, Vol. 43, No. 43, 21.11.2014, p. 16152-16155.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In4(μ2-OH)3} building block based metal organic framework through a dinuclear complex

AU - Wang, Xin Ming

AU - Fan, Rui Qing

AU - Qiang, Liang Sheng

AU - Wang, Ping

AU - Yang, Yu Lin

AU - Wang, Yu Lei

PY - 2014/11/21

Y1 - 2014/11/21

N2 - A rare 3D tetranuclear {In4(μ2-OH)3} building block based MOF {[In4/3(μ2-OH)(2,6-pydc)(1,4-bda)0.5(H2O)]·2H2O}n (2) was obtained through a crystal transformation from a dimeric complex In3(2,6-pydc)3(1,4-bda)1.5(H2O)6 (1). With a 2D + 3D → 3D compact structure, 2 retains crystallinity in boiling water and organic solvents, exhibiting exceptional fluorescence quenching behaviour for the DMSO molecule.

AB - A rare 3D tetranuclear {In4(μ2-OH)3} building block based MOF {[In4/3(μ2-OH)(2,6-pydc)(1,4-bda)0.5(H2O)]·2H2O}n (2) was obtained through a crystal transformation from a dimeric complex In3(2,6-pydc)3(1,4-bda)1.5(H2O)6 (1). With a 2D + 3D → 3D compact structure, 2 retains crystallinity in boiling water and organic solvents, exhibiting exceptional fluorescence quenching behaviour for the DMSO molecule.

UR - https://www.scopus.com/pages/publications/84908046970

U2 - 10.1039/c4dt02045f

DO - 10.1039/c4dt02045f

M3 - 文章

AN - SCOPUS:84908046970

SN - 1477-9226

VL - 43

SP - 16152

EP - 16155

JO - Dalton Transactions

JF - Dalton Transactions

IS - 43

ER -

Crystal transformation synthesis of a highly stable fluorescent 3D indium-tetranuclear {In₄(μ₂-OH)₃} building block based metal organic framework through a dinuclear complex

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