Crystal structures and third-order NLO properties in DMF solution of Co(II)-bpfp coordination polymers (bpfp = N,N′-bis(pyridylformyl) piperazine)

Hong Xu; Yinglin Song; Hongwei Hou

doi:10.1016/j.ica.2004.05.007

Crystal structures and third-order NLO properties in DMF solution of Co(II)-bpfp coordination polymers (bpfp = N,N′-bis(pyridylformyl) piperazine)

Hong Xu
, Yinglin Song
, Hongwei Hou^*

^*Corresponding author for this work

School of Physics

Zhengzhou University

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Two novel Co(ii) coordination polymers {[Co(H₂O) ₂(CH₃OH)₂(4-bpfp)](NO₃) ₂}_n 1 (4-bpfp=n,n^′-bis(4-pyridylformyl) piperazine) and [Co(NCS)₂(CH₃OH)₂(3-bpfp)] _n 2 (3-bpfp=N,N^′-bis(3-pyridylformyl)piperazine) have been synthesized and characterized by single crystal X-ray diffraction. Both the polymers consist of one-dimensional chains constructed by bridging bpfp ligands and Co(II) ions. The existence of O⋯H-O hydrogen bond in 1 and S⋯H-O hydrogen bond in 2 play important roles in creating interesting supramolecular structures. Their third-order nonlinear optical (NLO) properties in DMF solution have been studied by Z-scan technique. The results reveal that polymers 1 and 2 exhibit strong NLO absorption effects (α₂=9. 00×10^-11 m W^-1 for 1; 1.41×10^-10 m W^-1 for 2) and self-focusing performance (n₂=3. 24×10^-16 esu for 1; 3.05×10^-16 esu for 2) in DMF solutions. The corresponding effective NLO susceptibilities χ⁽³⁾ values are 3.08×10^-12 esu (1) and 4.70×10^-12 esu (2). All of the values are comparable to those of the reported good NLO materials. Additionally, the TG-DTA results of the two polymers are in agreement with the crystal structures.

Original language	English
Pages (from-to)	3541-3548
Number of pages	8
Journal	Inorganica Chimica Acta
Volume	357
Issue number	12
DOIs	https://doi.org/10.1016/j.ica.2004.05.007
State	Published - 10 Sep 2004

Keywords

Co(ii) coordination polymer
Crystal structure
Synthesis
Thermal response
Third-order nlo properties
n,n- bis(pyridylformyl)piperazine metal complexes

Access to Document

10.1016/j.ica.2004.05.007

Cite this

@article{8510e78576294b7da6621fd4f35e95bc,

title = "Crystal structures and third-order NLO properties in DMF solution of Co(II)-bpfp coordination polymers (bpfp = N,N′-bis(pyridylformyl) piperazine)",

abstract = "Two novel Co(ii) coordination polymers \{[Co(H2O) 2(CH3OH)2(4-bpfp)](NO3) 2\}n 1 (4-bpfp=n,n′-bis(4-pyridylformyl) piperazine) and [Co(NCS)2(CH3OH)2(3-bpfp)] n 2 (3-bpfp=N,N′-bis(3-pyridylformyl)piperazine) have been synthesized and characterized by single crystal X-ray diffraction. Both the polymers consist of one-dimensional chains constructed by bridging bpfp ligands and Co(II) ions. The existence of O⋯H-O hydrogen bond in 1 and S⋯H-O hydrogen bond in 2 play important roles in creating interesting supramolecular structures. Their third-order nonlinear optical (NLO) properties in DMF solution have been studied by Z-scan technique. The results reveal that polymers 1 and 2 exhibit strong NLO absorption effects (α2=9. 00{\texttimes}10-11 m W-1 for 1; 1.41{\texttimes}10-10 m W-1 for 2) and self-focusing performance (n2=3. 24{\texttimes}10-16 esu for 1; 3.05{\texttimes}10-16 esu for 2) in DMF solutions. The corresponding effective NLO susceptibilities χ(3) values are 3.08{\texttimes}10-12 esu (1) and 4.70{\texttimes}10-12 esu (2). All of the values are comparable to those of the reported good NLO materials. Additionally, the TG-DTA results of the two polymers are in agreement with the crystal structures.",

keywords = "Co(ii) coordination polymer, Crystal structure, Synthesis, Thermal response, Third-order nlo properties, n,n- bis(pyridylformyl)piperazine metal complexes",

author = "Hong Xu and Yinglin Song and Hongwei Hou",

year = "2004",

month = sep,

day = "10",

doi = "10.1016/j.ica.2004.05.007",

language = "英语",

volume = "357",

pages = "3541--3548",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

number = "12",

}

TY - JOUR

T1 - Crystal structures and third-order NLO properties in DMF solution of Co(II)-bpfp coordination polymers (bpfp = N,N′-bis(pyridylformyl) piperazine)

AU - Xu, Hong

AU - Song, Yinglin

AU - Hou, Hongwei

PY - 2004/9/10

Y1 - 2004/9/10

N2 - Two novel Co(ii) coordination polymers {[Co(H2O) 2(CH3OH)2(4-bpfp)](NO3) 2}n 1 (4-bpfp=n,n′-bis(4-pyridylformyl) piperazine) and [Co(NCS)2(CH3OH)2(3-bpfp)] n 2 (3-bpfp=N,N′-bis(3-pyridylformyl)piperazine) have been synthesized and characterized by single crystal X-ray diffraction. Both the polymers consist of one-dimensional chains constructed by bridging bpfp ligands and Co(II) ions. The existence of O⋯H-O hydrogen bond in 1 and S⋯H-O hydrogen bond in 2 play important roles in creating interesting supramolecular structures. Their third-order nonlinear optical (NLO) properties in DMF solution have been studied by Z-scan technique. The results reveal that polymers 1 and 2 exhibit strong NLO absorption effects (α2=9. 00×10-11 m W-1 for 1; 1.41×10-10 m W-1 for 2) and self-focusing performance (n2=3. 24×10-16 esu for 1; 3.05×10-16 esu for 2) in DMF solutions. The corresponding effective NLO susceptibilities χ(3) values are 3.08×10-12 esu (1) and 4.70×10-12 esu (2). All of the values are comparable to those of the reported good NLO materials. Additionally, the TG-DTA results of the two polymers are in agreement with the crystal structures.

AB - Two novel Co(ii) coordination polymers {[Co(H2O) 2(CH3OH)2(4-bpfp)](NO3) 2}n 1 (4-bpfp=n,n′-bis(4-pyridylformyl) piperazine) and [Co(NCS)2(CH3OH)2(3-bpfp)] n 2 (3-bpfp=N,N′-bis(3-pyridylformyl)piperazine) have been synthesized and characterized by single crystal X-ray diffraction. Both the polymers consist of one-dimensional chains constructed by bridging bpfp ligands and Co(II) ions. The existence of O⋯H-O hydrogen bond in 1 and S⋯H-O hydrogen bond in 2 play important roles in creating interesting supramolecular structures. Their third-order nonlinear optical (NLO) properties in DMF solution have been studied by Z-scan technique. The results reveal that polymers 1 and 2 exhibit strong NLO absorption effects (α2=9. 00×10-11 m W-1 for 1; 1.41×10-10 m W-1 for 2) and self-focusing performance (n2=3. 24×10-16 esu for 1; 3.05×10-16 esu for 2) in DMF solutions. The corresponding effective NLO susceptibilities χ(3) values are 3.08×10-12 esu (1) and 4.70×10-12 esu (2). All of the values are comparable to those of the reported good NLO materials. Additionally, the TG-DTA results of the two polymers are in agreement with the crystal structures.

KW - Co(ii) coordination polymer

KW - Crystal structure

KW - Synthesis

KW - Thermal response

KW - Third-order nlo properties

KW - n,n- bis(pyridylformyl)piperazine metal complexes

UR - https://www.scopus.com/pages/publications/4444350969

U2 - 10.1016/j.ica.2004.05.007

DO - 10.1016/j.ica.2004.05.007

M3 - 文章

AN - SCOPUS:4444350969

SN - 0020-1693

VL - 357

SP - 3541

EP - 3548

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

IS - 12

ER -

Crystal structures and third-order NLO properties in DMF solution of Co(II)-bpfp coordination polymers (bpfp = N,N′-bis(pyridylformyl) piperazine)

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this