Crystal Structure of Two V-shaped Ligands with N-Heterocycles

Gao Feng Wang; Shu Wen Sun; Xiao Zhang; Shu Gang Sun

doi:10.1134/S106377451707032X

Crystal Structure of Two V-shaped Ligands with N-Heterocycles

Gao Feng Wang^*
, Shu Wen Sun
, Xiao Zhang
, Shu Gang Sun

^*Corresponding author for this work

Yuncheng University
School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Xichang Satellite Launch Center

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Two V-shaped ligands with N-heterocycles, bis(4-(1H-imidazol-1-yl) phenyl)methanone (1), and bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone (2) have been synthesized and characterized by elemental analyses, IR and 1H NMR spectroscopy. Crystal structures of 1 and 2 have been determined by X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. P2₁/c, Z = 4. The crystal of 2 is orthorhombic, sp. gr. Fdd2, Z = 8. X-ray diffraction analyses show that the V-shaped angles of 1 and 2 are 122.72(15)° and 120.7(4)°, respectively. Intermolecular C–HO, C–HN, C–H, andinteractions link the components into three-dimensional networks in the crystal structures.

Original language	English
Pages (from-to)	1113-1117
Number of pages	5
Journal	Crystallography Reports
Volume	62
Issue number	7
DOIs	https://doi.org/10.1134/S106377451707032X
State	Published - 1 Dec 2017
Externally published	Yes

Access to Document

10.1134/S106377451707032X

Cite this

@article{b6d29f2eee8443e1a726e9b002934c2c,

title = "Crystal Structure of Two V-shaped Ligands with N-Heterocycles",

abstract = "Two V-shaped ligands with N-heterocycles, bis(4-(1H-imidazol-1-yl) phenyl)methanone (1), and bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone (2) have been synthesized and characterized by elemental analyses, IR and 1H NMR spectroscopy. Crystal structures of 1 and 2 have been determined by X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. P21/c, Z = 4. The crystal of 2 is orthorhombic, sp. gr. Fdd2, Z = 8. X-ray diffraction analyses show that the V-shaped angles of 1 and 2 are 122.72(15)° and 120.7(4)°, respectively. Intermolecular C–HO, C–HN, C–H, andinteractions link the components into three-dimensional networks in the crystal structures.",

author = "Wang, \{Gao Feng\} and Sun, \{Shu Wen\} and Xiao Zhang and Sun, \{Shu Gang\}",

note = "Publisher Copyright: {\textcopyright} 2017, Pleiades Publishing, Inc.",

year = "2017",

month = dec,

day = "1",

doi = "10.1134/S106377451707032X",

language = "英语",

volume = "62",

pages = "1113--1117",

journal = "Crystallography Reports",

issn = "1063-7745",

publisher = "Pleiades Publishing",

number = "7",

}

TY - JOUR

T1 - Crystal Structure of Two V-shaped Ligands with N-Heterocycles

AU - Wang, Gao Feng

AU - Sun, Shu Wen

AU - Zhang, Xiao

AU - Sun, Shu Gang

PY - 2017/12/1

Y1 - 2017/12/1

N2 - Two V-shaped ligands with N-heterocycles, bis(4-(1H-imidazol-1-yl) phenyl)methanone (1), and bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone (2) have been synthesized and characterized by elemental analyses, IR and 1H NMR spectroscopy. Crystal structures of 1 and 2 have been determined by X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. P21/c, Z = 4. The crystal of 2 is orthorhombic, sp. gr. Fdd2, Z = 8. X-ray diffraction analyses show that the V-shaped angles of 1 and 2 are 122.72(15)° and 120.7(4)°, respectively. Intermolecular C–HO, C–HN, C–H, andinteractions link the components into three-dimensional networks in the crystal structures.

AB - Two V-shaped ligands with N-heterocycles, bis(4-(1H-imidazol-1-yl) phenyl)methanone (1), and bis(4-(1H-benzo[d]imidazol-1-yl)phenyl)methanone (2) have been synthesized and characterized by elemental analyses, IR and 1H NMR spectroscopy. Crystal structures of 1 and 2 have been determined by X-ray diffraction. The crystal of 1 is monoclinic, sp. gr. P21/c, Z = 4. The crystal of 2 is orthorhombic, sp. gr. Fdd2, Z = 8. X-ray diffraction analyses show that the V-shaped angles of 1 and 2 are 122.72(15)° and 120.7(4)°, respectively. Intermolecular C–HO, C–HN, C–H, andinteractions link the components into three-dimensional networks in the crystal structures.

UR - https://www.scopus.com/pages/publications/85042558161

U2 - 10.1134/S106377451707032X

DO - 10.1134/S106377451707032X

M3 - 文章

AN - SCOPUS:85042558161

SN - 1063-7745

VL - 62

SP - 1113

EP - 1117

JO - Crystallography Reports

JF - Crystallography Reports

IS - 7

ER -

Crystal Structure of Two V-shaped Ligands with N-Heterocycles

Abstract

Access to Document

Other files and links

Fingerprint

Cite this