Crystal structure and nonlinear optical properties of cluster [WS 4Cu3Br(bipy)2]

Yue Hua Hu; He Gen Zheng; Kai Liang; Ying Lin Song; Yi Zhi Li; Xin Quan Xin

Crystal structure and nonlinear optical properties of cluster [WS ₄Cu₃Br(bipy)₂]

Yue Hua Hu^*
, He Gen Zheng
, Kai Liang
, Ying Lin Song
, Yi Zhi Li
, Xin Quan Xin

^*Corresponding author for this work

School of Physics

Huangshan College
Nanjing University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title cluster compound [WS₄Cu₃Br(bipy) ₂] has been synthesized by the reaction of (NH₄) ₂[WS₄], CuBr and 2, 2′-bipy in DMF solution. Single crystal X-ray diffraction data show that the compound has a nest-shaped structure. Nonlinear optical properties (NLO) of the cluster were investigated by a Z-scan technique with a pulsed laser at 532nm. The cluster exhibits the strong NLO absorption and a self-defocusing effect (effective non-linear absorption coefficient, α₂^eff = 7.3 × 10 ^-11mW^-1; effective non-linear refractive index, n ₂^eff = 3.9 × 10^-11esu) when measured in a 6.0 × 10^-4mol·dm^-3 DMF solution. CCDC: 200397.

Original language	English
Pages (from-to)	539-542
Number of pages	4
Journal	Chinese Journal of Inorganic Chemistry
Volume	19
Issue number	5
State	Published - 1 May 2003

Keywords

Crystal structure
Metal cluster
Nonlinear optical properties
Z-scan

Cite this

@article{7d6521bf78a64e52b9628874dd4491a0,

title = "Crystal structure and nonlinear optical properties of cluster [WS 4Cu3Br(bipy)2]",

abstract = "The title cluster compound [WS4Cu3Br(bipy) 2] has been synthesized by the reaction of (NH4) 2[WS4], CuBr and 2, 2′-bipy in DMF solution. Single crystal X-ray diffraction data show that the compound has a nest-shaped structure. Nonlinear optical properties (NLO) of the cluster were investigated by a Z-scan technique with a pulsed laser at 532nm. The cluster exhibits the strong NLO absorption and a self-defocusing effect (effective non-linear absorption coefficient, α2eff = 7.3 × 10 -11mW-1; effective non-linear refractive index, n 2eff = 3.9 × 10-11esu) when measured in a 6.0 × 10-4mol·dm-3 DMF solution. CCDC: 200397.",

keywords = "Crystal structure, Metal cluster, Nonlinear optical properties, Z-scan",

author = "Hu, \{Yue Hua\} and Zheng, \{He Gen\} and Kai Liang and Song, \{Ying Lin\} and Li, \{Yi Zhi\} and Xin, \{Xin Quan\}",

year = "2003",

month = may,

day = "1",

language = "英语",

volume = "19",

pages = "539--542",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

publisher = "Chinese Chemical Society",

number = "5",

}

TY - JOUR

T1 - Crystal structure and nonlinear optical properties of cluster [WS 4Cu3Br(bipy)2]

AU - Hu, Yue Hua

AU - Zheng, He Gen

AU - Liang, Kai

AU - Song, Ying Lin

AU - Li, Yi Zhi

AU - Xin, Xin Quan

PY - 2003/5/1

Y1 - 2003/5/1

N2 - The title cluster compound [WS4Cu3Br(bipy) 2] has been synthesized by the reaction of (NH4) 2[WS4], CuBr and 2, 2′-bipy in DMF solution. Single crystal X-ray diffraction data show that the compound has a nest-shaped structure. Nonlinear optical properties (NLO) of the cluster were investigated by a Z-scan technique with a pulsed laser at 532nm. The cluster exhibits the strong NLO absorption and a self-defocusing effect (effective non-linear absorption coefficient, α2eff = 7.3 × 10 -11mW-1; effective non-linear refractive index, n 2eff = 3.9 × 10-11esu) when measured in a 6.0 × 10-4mol·dm-3 DMF solution. CCDC: 200397.

AB - The title cluster compound [WS4Cu3Br(bipy) 2] has been synthesized by the reaction of (NH4) 2[WS4], CuBr and 2, 2′-bipy in DMF solution. Single crystal X-ray diffraction data show that the compound has a nest-shaped structure. Nonlinear optical properties (NLO) of the cluster were investigated by a Z-scan technique with a pulsed laser at 532nm. The cluster exhibits the strong NLO absorption and a self-defocusing effect (effective non-linear absorption coefficient, α2eff = 7.3 × 10 -11mW-1; effective non-linear refractive index, n 2eff = 3.9 × 10-11esu) when measured in a 6.0 × 10-4mol·dm-3 DMF solution. CCDC: 200397.

KW - Crystal structure

KW - Metal cluster

KW - Nonlinear optical properties

KW - Z-scan

UR - https://www.scopus.com/pages/publications/0141739251

M3 - 文章

AN - SCOPUS:0141739251

SN - 1001-4861

VL - 19

SP - 539

EP - 542

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 5

ER -

Crystal structure and nonlinear optical properties of cluster [WS ₄Cu₃Br(bipy)₂]

Abstract

Keywords

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