Crystal structure and electrochemical properties of the supramolecular compound [Himi]6[As2Mo18O62] ·11H2O

Yanyan Yang; Lin Xu; Liping Jia; Guanggang Gao; Fengyan Li; Xiaoshu Qu; Yunfeng Qiu

doi:10.1002/crat.200710937

Crystal structure and electrochemical properties of the supramolecular compound [Himi]₆[As₂Mo₁₈O₆₂] ·11H₂O

Yanyan Yang
, Lin Xu^*
, Liping Jia
, Guanggang Gao
, Fengyan Li
, Xiaoshu Qu
, Yunfeng Qiu

^*Corresponding author for this work

Northeast Normal University

Research output: Contribution to journal › Article › peer-review

21 Scopus citations

Abstract

A supramolecular compound, [Himi]₆[As₂Mo ₁₈O₆₂]·11H₂O (1) (imi = imidazole), has been synthesized and characterized by single crystal X-ray analysis, IR spectra, thermal gravimetric analysis, electrochemical and elemental analysis. The crystals are monoclinic, P 2(1)/n, a = 14.9529(8) Å, b = 20.9521(11) Å, c = 25.2464(13) Å, β= 93.8130(10)°, V = 7892.1(7) Å³, Z = 4. X-ray diffraction indicated that protonated imidazole cation and polyanion were linked together through electrostatic interactions and intermolecular forces (hydrogen bonding).

Original language	English
Pages (from-to)	1036-1040
Number of pages	5
Journal	Crystal Research and Technology
Volume	42
Issue number	10
DOIs	https://doi.org/10.1002/crat.200710937
State	Published - Oct 2007
Externally published	Yes

Keywords

Arsenic
Dawson type polyoxometalate
Imidazole
Molybdenum

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10.1002/crat.200710937

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@article{f376321a34cd46de8fcdd3b0bfd29ae6,

title = "Crystal structure and electrochemical properties of the supramolecular compound [Himi]6[As2Mo18O62] ·11H2O",

abstract = "A supramolecular compound, [Himi]6[As2Mo 18O62]·11H2O (1) (imi = imidazole), has been synthesized and characterized by single crystal X-ray analysis, IR spectra, thermal gravimetric analysis, electrochemical and elemental analysis. The crystals are monoclinic, P 2(1)/n, a = 14.9529(8) {\AA}, b = 20.9521(11) {\AA}, c = 25.2464(13) {\AA}, β= 93.8130(10)°, V = 7892.1(7) {\AA}3, Z = 4. X-ray diffraction indicated that protonated imidazole cation and polyanion were linked together through electrostatic interactions and intermolecular forces (hydrogen bonding).",

keywords = "Arsenic, Dawson type polyoxometalate, Imidazole, Molybdenum",

author = "Yanyan Yang and Lin Xu and Liping Jia and Guanggang Gao and Fengyan Li and Xiaoshu Qu and Yunfeng Qiu",

year = "2007",

month = oct,

doi = "10.1002/crat.200710937",

language = "英语",

volume = "42",

pages = "1036--1040",

journal = "Crystal Research and Technology",

issn = "0232-1300",

publisher = "John Wiley \& Sons Inc.",

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TY - JOUR

T1 - Crystal structure and electrochemical properties of the supramolecular compound [Himi]6[As2Mo18O62] ·11H2O

AU - Yang, Yanyan

AU - Xu, Lin

AU - Jia, Liping

AU - Gao, Guanggang

AU - Li, Fengyan

AU - Qu, Xiaoshu

AU - Qiu, Yunfeng

PY - 2007/10

Y1 - 2007/10

N2 - A supramolecular compound, [Himi]6[As2Mo 18O62]·11H2O (1) (imi = imidazole), has been synthesized and characterized by single crystal X-ray analysis, IR spectra, thermal gravimetric analysis, electrochemical and elemental analysis. The crystals are monoclinic, P 2(1)/n, a = 14.9529(8) Å, b = 20.9521(11) Å, c = 25.2464(13) Å, β= 93.8130(10)°, V = 7892.1(7) Å3, Z = 4. X-ray diffraction indicated that protonated imidazole cation and polyanion were linked together through electrostatic interactions and intermolecular forces (hydrogen bonding).

AB - A supramolecular compound, [Himi]6[As2Mo 18O62]·11H2O (1) (imi = imidazole), has been synthesized and characterized by single crystal X-ray analysis, IR spectra, thermal gravimetric analysis, electrochemical and elemental analysis. The crystals are monoclinic, P 2(1)/n, a = 14.9529(8) Å, b = 20.9521(11) Å, c = 25.2464(13) Å, β= 93.8130(10)°, V = 7892.1(7) Å3, Z = 4. X-ray diffraction indicated that protonated imidazole cation and polyanion were linked together through electrostatic interactions and intermolecular forces (hydrogen bonding).

KW - Arsenic

KW - Dawson type polyoxometalate

KW - Imidazole

KW - Molybdenum

UR - https://www.scopus.com/pages/publications/35248819269

U2 - 10.1002/crat.200710937

DO - 10.1002/crat.200710937

M3 - 文章

AN - SCOPUS:35248819269

SN - 0232-1300

VL - 42

SP - 1036

EP - 1040

JO - Crystal Research and Technology

JF - Crystal Research and Technology

IS - 10

ER -

Crystal structure and electrochemical properties of the supramolecular compound [Himi]₆[As₂Mo₁₈O₆₂] ·11H₂O

Abstract

Keywords

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