Critical catenation concentration of a polyoxometalate–organic cage

Shicheng Han; Yuan Gao; Gang Fu; Ji Guo; Xikui Fang

doi:10.1039/d6cc02792j

Critical catenation concentration of a polyoxometalate–organic cage

Shicheng Han
, Yuan Gao
, Gang Fu^*
, Ji Guo
, Xikui Fang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Yili Normal University

Research output: Contribution to journal › Article › peer-review

Abstract

The conversion between a polyoxovanadate–organic cage and its triply interlocked [2]catenane can be deliberately controlled by varying the concentration of building blocks under solvothermal conditions. ESI-MS results revealed that the concentration-induced interlocking phenomenon occurs abruptly at a critical concentration of 16.7 mM (based on organic ligands) instead of a more progressive shift.

Original language	English
Pages (from-to)	15714-15718
Number of pages	5
Journal	Chemical Communications
Volume	62
Issue number	63
DOIs	https://doi.org/10.1039/d6cc02792j
State	Published - 13 Aug 2026
Externally published	Yes

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10.1039/d6cc02792j

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title = "Critical catenation concentration of a polyoxometalate{\textendash}organic cage",

abstract = "The conversion between a polyoxovanadate{\textendash}organic cage and its triply interlocked [2]catenane can be deliberately controlled by varying the concentration of building blocks under solvothermal conditions. ESI-MS results revealed that the concentration-induced interlocking phenomenon occurs abruptly at a critical concentration of 16.7 mM (based on organic ligands) instead of a more progressive shift.",

author = "Shicheng Han and Yuan Gao and Gang Fu and Ji Guo and Xikui Fang",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry, 2026.",

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doi = "10.1039/d6cc02792j",

language = "英语",

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AU - Han, Shicheng

AU - Gao, Yuan

AU - Fu, Gang

AU - Guo, Ji

AU - Fang, Xikui

N1 - Publisher Copyright: This journal is © The Royal Society of Chemistry, 2026.

PY - 2026/8/13

Y1 - 2026/8/13

N2 - The conversion between a polyoxovanadate–organic cage and its triply interlocked [2]catenane can be deliberately controlled by varying the concentration of building blocks under solvothermal conditions. ESI-MS results revealed that the concentration-induced interlocking phenomenon occurs abruptly at a critical concentration of 16.7 mM (based on organic ligands) instead of a more progressive shift.

AB - The conversion between a polyoxovanadate–organic cage and its triply interlocked [2]catenane can be deliberately controlled by varying the concentration of building blocks under solvothermal conditions. ESI-MS results revealed that the concentration-induced interlocking phenomenon occurs abruptly at a critical concentration of 16.7 mM (based on organic ligands) instead of a more progressive shift.

UR - https://www.scopus.com/pages/publications/105046048667

U2 - 10.1039/d6cc02792j

DO - 10.1039/d6cc02792j

M3 - 文章

C2 - 42483902

AN - SCOPUS:105046048667

SN - 1359-7345

VL - 62

SP - 15714

EP - 15718

JO - Chemical Communications

JF - Chemical Communications

IS - 63

ER -

Critical catenation concentration of a polyoxometalate–organic cage

Abstract

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