Cr effects on magnetic and corrosion properties of Fe-Co-Si-B-Nb-Cr bulk glassy alloys with high glass-forming ability

Z. L. Long; Y. Shao; X. H. Deng; Z. C. Zhang; Y. Jiang; P. Zhang; B. L. Shen; A. Inoue

doi:10.1016/j.intermet.2007.05.002

Cr effects on magnetic and corrosion properties of Fe-Co-Si-B-Nb-Cr bulk glassy alloys with high glass-forming ability

Z. L. Long^*
, Y. Shao
, X. H. Deng
, Z. C. Zhang
, Y. Jiang
, P. Zhang
, B. L. Shen
, A. Inoue

^*Corresponding author for this work

XiangTan University
Tohoku University

Research output: Contribution to journal › Article › peer-review

99 Scopus citations

Abstract

Effects of the Cr addition on glass formation, magnetic and corrosion properties of {[(Fe_0.6Co_0.4)_0.75B_0.2Si_0.05]_0.96Nb_0.04}_100-xCr_x (x = 1, 2, 3, 4 at.%) alloys have been investigated. It was found that the addition of Cr element slightly decreases the glass-forming ability (GFA), but is very effective in increasing corrosion resistance and improving soft magnetic properties for this Fe-Co-B-Si-Nb bulk glassy alloy within the composition range examined. The Fe-Co-B-Si-Nb-Cr alloys exhibit high GFA. Full glassy rods with diameters up to 4 mm can be synthesized by copper mold casting. The Fe-based bulk glassy alloys (BGAs) exhibit a high saturation magnetization of 0.81-0.98 T as well as excellent soft magnetic properties, i.e., extremely low coercive force of 0.6-1.6 A/m and super-high initial permeability of 26,400-34,100. Furthermore, corrosion measurements show that corrosion rate and corrosion current density of these Fe-based BGAs in 0.5 M NaCl solution decrease from 7.0 × 10^-1 to 1.6 × 10^-3 mm/year and 3.9 × 10^-6 to 8.7 × 10^-7 A/cm², respectively, with increasing Cr content from 0 to 4 at.%. The success of synthesizing the new Fe-based BGAs exhibiting simultaneously high GFA as well as excellent good soft magnetic properties combined with high saturation magnetization and enhanced corrosion resistance allows us to expect future progress as a new type of soft magnetic materials.

Original language	English
Pages (from-to)	1453-1458
Number of pages	6
Journal	Intermetallics
Volume	15
Issue number	11
DOIs	https://doi.org/10.1016/j.intermet.2007.05.002
State	Published - Nov 2007
Externally published	Yes

Keywords

B. Glasses, metallic
B. Magnetic properties
F. Corrosion behaviour

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10.1016/j.intermet.2007.05.002

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@article{dcbb4e1b69654a84b250400391a1c10e,

title = "Cr effects on magnetic and corrosion properties of Fe-Co-Si-B-Nb-Cr bulk glassy alloys with high glass-forming ability",

abstract = "Effects of the Cr addition on glass formation, magnetic and corrosion properties of \{[(Fe0.6Co0.4)0.75B0.2Si0.05]0.96Nb0.04\}100-xCrx (x = 1, 2, 3, 4 at.\%) alloys have been investigated. It was found that the addition of Cr element slightly decreases the glass-forming ability (GFA), but is very effective in increasing corrosion resistance and improving soft magnetic properties for this Fe-Co-B-Si-Nb bulk glassy alloy within the composition range examined. The Fe-Co-B-Si-Nb-Cr alloys exhibit high GFA. Full glassy rods with diameters up to 4 mm can be synthesized by copper mold casting. The Fe-based bulk glassy alloys (BGAs) exhibit a high saturation magnetization of 0.81-0.98 T as well as excellent soft magnetic properties, i.e., extremely low coercive force of 0.6-1.6 A/m and super-high initial permeability of 26,400-34,100. Furthermore, corrosion measurements show that corrosion rate and corrosion current density of these Fe-based BGAs in 0.5 M NaCl solution decrease from 7.0 × 10-1 to 1.6 × 10-3 mm/year and 3.9 × 10-6 to 8.7 × 10-7 A/cm2, respectively, with increasing Cr content from 0 to 4 at.\%. The success of synthesizing the new Fe-based BGAs exhibiting simultaneously high GFA as well as excellent good soft magnetic properties combined with high saturation magnetization and enhanced corrosion resistance allows us to expect future progress as a new type of soft magnetic materials.",

keywords = "B. Glasses, metallic, B. Magnetic properties, F. Corrosion behaviour",

author = "Long, \{Z. L.\} and Y. Shao and Deng, \{X. H.\} and Zhang, \{Z. C.\} and Y. Jiang and P. Zhang and Shen, \{B. L.\} and A. Inoue",

year = "2007",

month = nov,

doi = "10.1016/j.intermet.2007.05.002",

language = "英语",

volume = "15",

pages = "1453--1458",

journal = "Intermetallics",

issn = "0966-9795",

publisher = "Elsevier Ltd",

number = "11",

}

TY - JOUR

T1 - Cr effects on magnetic and corrosion properties of Fe-Co-Si-B-Nb-Cr bulk glassy alloys with high glass-forming ability

AU - Long, Z. L.

AU - Shao, Y.

AU - Deng, X. H.

AU - Zhang, Z. C.

AU - Jiang, Y.

AU - Zhang, P.

AU - Shen, B. L.

AU - Inoue, A.

PY - 2007/11

Y1 - 2007/11

N2 - Effects of the Cr addition on glass formation, magnetic and corrosion properties of {[(Fe0.6Co0.4)0.75B0.2Si0.05]0.96Nb0.04}100-xCrx (x = 1, 2, 3, 4 at.%) alloys have been investigated. It was found that the addition of Cr element slightly decreases the glass-forming ability (GFA), but is very effective in increasing corrosion resistance and improving soft magnetic properties for this Fe-Co-B-Si-Nb bulk glassy alloy within the composition range examined. The Fe-Co-B-Si-Nb-Cr alloys exhibit high GFA. Full glassy rods with diameters up to 4 mm can be synthesized by copper mold casting. The Fe-based bulk glassy alloys (BGAs) exhibit a high saturation magnetization of 0.81-0.98 T as well as excellent soft magnetic properties, i.e., extremely low coercive force of 0.6-1.6 A/m and super-high initial permeability of 26,400-34,100. Furthermore, corrosion measurements show that corrosion rate and corrosion current density of these Fe-based BGAs in 0.5 M NaCl solution decrease from 7.0 × 10-1 to 1.6 × 10-3 mm/year and 3.9 × 10-6 to 8.7 × 10-7 A/cm2, respectively, with increasing Cr content from 0 to 4 at.%. The success of synthesizing the new Fe-based BGAs exhibiting simultaneously high GFA as well as excellent good soft magnetic properties combined with high saturation magnetization and enhanced corrosion resistance allows us to expect future progress as a new type of soft magnetic materials.

AB - Effects of the Cr addition on glass formation, magnetic and corrosion properties of {[(Fe0.6Co0.4)0.75B0.2Si0.05]0.96Nb0.04}100-xCrx (x = 1, 2, 3, 4 at.%) alloys have been investigated. It was found that the addition of Cr element slightly decreases the glass-forming ability (GFA), but is very effective in increasing corrosion resistance and improving soft magnetic properties for this Fe-Co-B-Si-Nb bulk glassy alloy within the composition range examined. The Fe-Co-B-Si-Nb-Cr alloys exhibit high GFA. Full glassy rods with diameters up to 4 mm can be synthesized by copper mold casting. The Fe-based bulk glassy alloys (BGAs) exhibit a high saturation magnetization of 0.81-0.98 T as well as excellent soft magnetic properties, i.e., extremely low coercive force of 0.6-1.6 A/m and super-high initial permeability of 26,400-34,100. Furthermore, corrosion measurements show that corrosion rate and corrosion current density of these Fe-based BGAs in 0.5 M NaCl solution decrease from 7.0 × 10-1 to 1.6 × 10-3 mm/year and 3.9 × 10-6 to 8.7 × 10-7 A/cm2, respectively, with increasing Cr content from 0 to 4 at.%. The success of synthesizing the new Fe-based BGAs exhibiting simultaneously high GFA as well as excellent good soft magnetic properties combined with high saturation magnetization and enhanced corrosion resistance allows us to expect future progress as a new type of soft magnetic materials.

KW - B. Glasses, metallic

KW - B. Magnetic properties

KW - F. Corrosion behaviour

UR - https://www.scopus.com/pages/publications/34547110541

U2 - 10.1016/j.intermet.2007.05.002

DO - 10.1016/j.intermet.2007.05.002

M3 - 文章

AN - SCOPUS:34547110541

SN - 0966-9795

VL - 15

SP - 1453

EP - 1458

JO - Intermetallics

JF - Intermetallics

IS - 11

ER -

Cr effects on magnetic and corrosion properties of Fe-Co-Si-B-Nb-Cr bulk glassy alloys with high glass-forming ability

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Keywords

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