Construction of variable dimension green high energy complex and laser response

Wenjia Hao; Bo Jin; Jinhao Zhang; Liqiong Luo; Quancheng Liu; Hu Deng; Tao Huang; Li Liu; Juan Shen; Rufang Peng

doi:10.1016/j.molstruc.2023.135036

Construction of variable dimension green high energy complex and laser response

Wenjia Hao
, Bo Jin^*
, Jinhao Zhang
, Liqiong Luo
, Quancheng Liu
, Hu Deng
, Tao Huang
, Li Liu
, Juan Shen
, Rufang Peng

^*Corresponding author for this work

Southwest University of Science and Technology

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A high dimensional energetic complex [Co(OH-Tz)₂(H₂O)₂]_n was synthesis with tetrazole energetic ligand, and its single crystal structures were obtained. Compared with the previously reported complexes, it has higher density (ρ = 2.135 g·cm⁻³), higher energy level (D = 7.59 km·s⁻¹) and thermal stability (T_dec = 271 ℃). In addition, the femtosecond laser and high-speed imaging results show that this compound is sensitive to laser stimulation, and under the stimulation of 808 nm femtosecond laser, the detonation process initiated by thermal mechanism can occur when the total laser energy is 224 mJ. Therefore, it is a potential environment-friendly laser detonating material.

Original language	English
Article number	135036
Journal	Journal of Molecular Structure
Volume	1281
DOIs	https://doi.org/10.1016/j.molstruc.2023.135036
State	Published - 5 Jun 2023
Externally published	Yes

Keywords

Crystal structure
Energetic metal organic framework
Laser initiation
Tetrazole

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10.1016/j.molstruc.2023.135036

Cite this

@article{8992a96989664d5c8e02c69e0deb5a35,

title = "Construction of variable dimension green high energy complex and laser response",

abstract = "A high dimensional energetic complex [Co(OH-Tz)2(H2O)2]n was synthesis with tetrazole energetic ligand, and its single crystal structures were obtained. Compared with the previously reported complexes, it has higher density (ρ = 2.135 g·cm−3), higher energy level (D = 7.59 km·s−1) and thermal stability (Tdec = 271 ℃). In addition, the femtosecond laser and high-speed imaging results show that this compound is sensitive to laser stimulation, and under the stimulation of 808 nm femtosecond laser, the detonation process initiated by thermal mechanism can occur when the total laser energy is 224 mJ. Therefore, it is a potential environment-friendly laser detonating material.",

keywords = "Crystal structure, Energetic metal organic framework, Laser initiation, Tetrazole",

author = "Wenjia Hao and Bo Jin and Jinhao Zhang and Liqiong Luo and Quancheng Liu and Hu Deng and Tao Huang and Li Liu and Juan Shen and Rufang Peng",

note = "Publisher Copyright: {\textcopyright} 2023",

year = "2023",

month = jun,

day = "5",

doi = "10.1016/j.molstruc.2023.135036",

language = "英语",

volume = "1281",

journal = "Journal of Molecular Structure",

issn = "0022-2860",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Construction of variable dimension green high energy complex and laser response

AU - Hao, Wenjia

AU - Jin, Bo

AU - Zhang, Jinhao

AU - Luo, Liqiong

AU - Liu, Quancheng

AU - Deng, Hu

AU - Huang, Tao

AU - Liu, Li

AU - Shen, Juan

AU - Peng, Rufang

PY - 2023/6/5

Y1 - 2023/6/5

N2 - A high dimensional energetic complex [Co(OH-Tz)2(H2O)2]n was synthesis with tetrazole energetic ligand, and its single crystal structures were obtained. Compared with the previously reported complexes, it has higher density (ρ = 2.135 g·cm−3), higher energy level (D = 7.59 km·s−1) and thermal stability (Tdec = 271 ℃). In addition, the femtosecond laser and high-speed imaging results show that this compound is sensitive to laser stimulation, and under the stimulation of 808 nm femtosecond laser, the detonation process initiated by thermal mechanism can occur when the total laser energy is 224 mJ. Therefore, it is a potential environment-friendly laser detonating material.

AB - A high dimensional energetic complex [Co(OH-Tz)2(H2O)2]n was synthesis with tetrazole energetic ligand, and its single crystal structures were obtained. Compared with the previously reported complexes, it has higher density (ρ = 2.135 g·cm−3), higher energy level (D = 7.59 km·s−1) and thermal stability (Tdec = 271 ℃). In addition, the femtosecond laser and high-speed imaging results show that this compound is sensitive to laser stimulation, and under the stimulation of 808 nm femtosecond laser, the detonation process initiated by thermal mechanism can occur when the total laser energy is 224 mJ. Therefore, it is a potential environment-friendly laser detonating material.

KW - Crystal structure

KW - Energetic metal organic framework

KW - Laser initiation

KW - Tetrazole

UR - https://www.scopus.com/pages/publications/85147976818

U2 - 10.1016/j.molstruc.2023.135036

DO - 10.1016/j.molstruc.2023.135036

M3 - 文章

AN - SCOPUS:85147976818

SN - 0022-2860

VL - 1281

JO - Journal of Molecular Structure

JF - Journal of Molecular Structure

M1 - 135036

ER -

Construction of variable dimension green high energy complex and laser response

Abstract

Keywords

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