Construction of Moiré-like Structure to Efficiently Enhance the H₂ Photogeneration

Photocatalytic hydrogen production could sustainably and efficiently convert solar energy. However, a low light utilization ratio limits the wide application. Herein, a Moiré-like structure was constructed in the TiO₂ body to improve the light absorption by multiple reflections and suitable light dispersion and diffraction based on similar wavelength and nick. Furthermore, the Moiré-like structure slightly reduces the band gap and accelerates the separation of the photogenerated electrons and holes, and the mass transfer was enhanced by the regular nano-channels and Bernoulli phenomenon. After calcination at 500 °C (M-T500), compared with pure TiO₂, M-T500 achieved a 20% increase in RhB degradation efficiency and a double increase in hydrogen production rate, thus providing a novel design for catalysts and a high catalytic strategy. Moreover, the nearly 100% recovery rate supported environmental protection and sustainable development.