Composite sorbent based on Fe3O4 with Fe(N2H4)xCly for the removal of Chromium(VI) from wastewater

Denis P. Ordinartsev; Nadezhda V. Pechishcheva; Svetlana Kh Estemirova; Angelina V. Kim; Evgenii V. Sterkhov; Sofia A. Petrova; Galina A. Shilenko

doi:10.17586/2220-8054-2024-15-4-510-519

Composite sorbent based on Fe₃O₄ with Fe(N₂H₄)_xCl_y for the removal of Chromium(VI) from wastewater

Denis P. Ordinartsev^*
, Nadezhda V. Pechishcheva
, Svetlana Kh Estemirova
, Angelina V. Kim
, Evgenii V. Sterkhov
, Sofia A. Petrova
, Galina A. Shilenko

^*Corresponding author for this work

Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
Ural Federal University

Research output: Contribution to journal › Article › peer-review

Abstract

The paper presents a methodology for the synthesis of iron complex with hydrazine hydrate Fe(N₂H₄)_xCl_y. The Fe(N₂H₄)_xCl_y complex was investigated by X-ray phase analysis and scanning electron microscopy. Upon hydrolysis, the Fe(N₂H₄)_xCl_y complex forms a composite sorbent, which is Fe₃O₄ in a shell of Fe(N₂H₄)_xCl_y complex. The composite sorbent can be used to treat wastewater from Cr(VI) ions and is effective in the pH range of 2 to 12. Based on the adsorption and electrokinetic potential data, a conclusion about the nature of the terminal groups of the adsorbent was made, a scheme of the structure of its electrical double layer and the adsorption mechanism were proposed. Depending on the conditions, Cr(VI) can be adsorbed on the composite sorbent or reduced to Cr(III). The efficiency of the composite sorbent in the removal of Cr(VI) ions was tested on a sample of real wastewater.

Original language	English
Pages (from-to)	510-519
Number of pages	10
Journal	Nanosystems: Physics, Chemistry, Mathematics
Volume	15
Issue number	4
DOIs	https://doi.org/10.17586/2220-8054-2024-15-4-510-519
State	Published - Aug 2024
Externally published	Yes

Keywords

Iron complex with hydrazine
adsorption isotherms
chromium adsorption
heavy metals
magnetite sol

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10.17586/2220-8054-2024-15-4-510-519

Cite this

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title = "Composite sorbent based on Fe3O4 with Fe(N2H4)xCly for the removal of Chromium(VI) from wastewater",

abstract = "The paper presents a methodology for the synthesis of iron complex with hydrazine hydrate Fe(N2H4)xCly. The Fe(N2H4)xCly complex was investigated by X-ray phase analysis and scanning electron microscopy. Upon hydrolysis, the Fe(N2H4)xCly complex forms a composite sorbent, which is Fe3O4 in a shell of Fe(N2H4)xCly complex. The composite sorbent can be used to treat wastewater from Cr(VI) ions and is effective in the pH range of 2 to 12. Based on the adsorption and electrokinetic potential data, a conclusion about the nature of the terminal groups of the adsorbent was made, a scheme of the structure of its electrical double layer and the adsorption mechanism were proposed. Depending on the conditions, Cr(VI) can be adsorbed on the composite sorbent or reduced to Cr(III). The efficiency of the composite sorbent in the removal of Cr(VI) ions was tested on a sample of real wastewater.",

keywords = "Iron complex with hydrazine, adsorption isotherms, chromium adsorption, heavy metals, magnetite sol",

author = "Ordinartsev, \{Denis P.\} and Pechishcheva, \{Nadezhda V.\} and Estemirova, \{Svetlana Kh\} and Kim, \{Angelina V.\} and Sterkhov, \{Evgenii V.\} and Petrova, \{Sofia A.\} and Shilenko, \{Galina A.\}",

note = "Publisher Copyright: {\textcopyright} Ordinartsev D.P., Pechishcheva N.V., Estemirova S.Kh., Kim A.V., Sterkhov E.V., Petrova S.A., Shilenko G.A., 2024.",

year = "2024",

month = aug,

doi = "10.17586/2220-8054-2024-15-4-510-519",

language = "英语",

volume = "15",

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journal = "Nanosystems: Physics, Chemistry, Mathematics",

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TY - JOUR

T1 - Composite sorbent based on Fe3O4 with Fe(N2H4)xCly for the removal of Chromium(VI) from wastewater

AU - Ordinartsev, Denis P.

AU - Pechishcheva, Nadezhda V.

AU - Estemirova, Svetlana Kh

AU - Kim, Angelina V.

AU - Sterkhov, Evgenii V.

AU - Petrova, Sofia A.

AU - Shilenko, Galina A.

N1 - Publisher Copyright: © Ordinartsev D.P., Pechishcheva N.V., Estemirova S.Kh., Kim A.V., Sterkhov E.V., Petrova S.A., Shilenko G.A., 2024.

PY - 2024/8

Y1 - 2024/8

N2 - The paper presents a methodology for the synthesis of iron complex with hydrazine hydrate Fe(N2H4)xCly. The Fe(N2H4)xCly complex was investigated by X-ray phase analysis and scanning electron microscopy. Upon hydrolysis, the Fe(N2H4)xCly complex forms a composite sorbent, which is Fe3O4 in a shell of Fe(N2H4)xCly complex. The composite sorbent can be used to treat wastewater from Cr(VI) ions and is effective in the pH range of 2 to 12. Based on the adsorption and electrokinetic potential data, a conclusion about the nature of the terminal groups of the adsorbent was made, a scheme of the structure of its electrical double layer and the adsorption mechanism were proposed. Depending on the conditions, Cr(VI) can be adsorbed on the composite sorbent or reduced to Cr(III). The efficiency of the composite sorbent in the removal of Cr(VI) ions was tested on a sample of real wastewater.

AB - The paper presents a methodology for the synthesis of iron complex with hydrazine hydrate Fe(N2H4)xCly. The Fe(N2H4)xCly complex was investigated by X-ray phase analysis and scanning electron microscopy. Upon hydrolysis, the Fe(N2H4)xCly complex forms a composite sorbent, which is Fe3O4 in a shell of Fe(N2H4)xCly complex. The composite sorbent can be used to treat wastewater from Cr(VI) ions and is effective in the pH range of 2 to 12. Based on the adsorption and electrokinetic potential data, a conclusion about the nature of the terminal groups of the adsorbent was made, a scheme of the structure of its electrical double layer and the adsorption mechanism were proposed. Depending on the conditions, Cr(VI) can be adsorbed on the composite sorbent or reduced to Cr(III). The efficiency of the composite sorbent in the removal of Cr(VI) ions was tested on a sample of real wastewater.

KW - Iron complex with hydrazine

KW - adsorption isotherms

KW - chromium adsorption

KW - heavy metals

KW - magnetite sol

UR - https://www.scopus.com/pages/publications/85203514148

U2 - 10.17586/2220-8054-2024-15-4-510-519

DO - 10.17586/2220-8054-2024-15-4-510-519

M3 - 文章

AN - SCOPUS:85203514148

SN - 2220-8054

VL - 15

SP - 510

EP - 519

JO - Nanosystems: Physics, Chemistry, Mathematics

JF - Nanosystems: Physics, Chemistry, Mathematics

IS - 4

ER -

Composite sorbent based on Fe₃O₄ with Fe(N₂H₄)_xCl_y for the removal of Chromium(VI) from wastewater

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Keywords

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