Communication: Tracking molecular structure deformation and relaxation in real time

Y. Wang; W. L. Liu; Y. F. Song; Y. Q. Liu; L. P. Duo; L. L. Jiang; G. Y. Yu; Y. Q. Yang

doi:10.1063/1.4927918

Communication: Tracking molecular structure deformation and relaxation in real time

Y. Wang
, W. L. Liu
, Y. F. Song
, Y. Q. Liu
, L. P. Duo
, L. L. Jiang
, G. Y. Yu
, Y. Q. Yang^*

^*Corresponding author for this work

School of Physics

Harbin Institute of Technology
CAS - Dalian Institute of Chemical Physics
China Academy of Engineering Physics

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

The CH₃I structural deformation induced by strong laser fields is revealed by time- and frequency-resolved ro-vibrational spectra. The experimental results show that the CH₃I molecule undergoes ultrafast structural deformation of CH₃ "umbrella-closing" induced by the strong fs laser field (more than 10¹¹ W/cm²) and followed by a structural relaxation of "umbrella-opening" within an exponential decay time scale of ∼620 fs. This study provides a first glimpse of the immense potential of the time- and frequency-resolved vibrational spectra in studying molecular deformation dynamics.

Original language	English
Article number	051101
Journal	Journal of Chemical Physics
Volume	143
Issue number	5
DOIs	https://doi.org/10.1063/1.4927918
State	Published - 7 Aug 2015

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10.1063/1.4927918

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@article{fd29bf8bb8a540a2b956055c76fd1079,

title = "Communication: Tracking molecular structure deformation and relaxation in real time",

abstract = "The CH3I structural deformation induced by strong laser fields is revealed by time- and frequency-resolved ro-vibrational spectra. The experimental results show that the CH3I molecule undergoes ultrafast structural deformation of CH3 {"}umbrella-closing{"} induced by the strong fs laser field (more than 1011 W/cm2) and followed by a structural relaxation of {"}umbrella-opening{"} within an exponential decay time scale of ∼620 fs. This study provides a first glimpse of the immense potential of the time- and frequency-resolved vibrational spectra in studying molecular deformation dynamics.",

author = "Y. Wang and Liu, \{W. L.\} and Song, \{Y. F.\} and Liu, \{Y. Q.\} and Duo, \{L. P.\} and Jiang, \{L. L.\} and Yu, \{G. Y.\} and Yang, \{Y. Q.\}",

note = "Publisher Copyright: {\textcopyright} 2015 AIP Publishing LLC.",

year = "2015",

month = aug,

day = "7",

doi = "10.1063/1.4927918",

language = "英语",

volume = "143",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

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TY - JOUR

T1 - Communication

T2 - Tracking molecular structure deformation and relaxation in real time

AU - Wang, Y.

AU - Liu, W. L.

AU - Song, Y. F.

AU - Liu, Y. Q.

AU - Duo, L. P.

AU - Jiang, L. L.

AU - Yu, G. Y.

AU - Yang, Y. Q.

PY - 2015/8/7

Y1 - 2015/8/7

N2 - The CH3I structural deformation induced by strong laser fields is revealed by time- and frequency-resolved ro-vibrational spectra. The experimental results show that the CH3I molecule undergoes ultrafast structural deformation of CH3 "umbrella-closing" induced by the strong fs laser field (more than 1011 W/cm2) and followed by a structural relaxation of "umbrella-opening" within an exponential decay time scale of ∼620 fs. This study provides a first glimpse of the immense potential of the time- and frequency-resolved vibrational spectra in studying molecular deformation dynamics.

AB - The CH3I structural deformation induced by strong laser fields is revealed by time- and frequency-resolved ro-vibrational spectra. The experimental results show that the CH3I molecule undergoes ultrafast structural deformation of CH3 "umbrella-closing" induced by the strong fs laser field (more than 1011 W/cm2) and followed by a structural relaxation of "umbrella-opening" within an exponential decay time scale of ∼620 fs. This study provides a first glimpse of the immense potential of the time- and frequency-resolved vibrational spectra in studying molecular deformation dynamics.

UR - https://www.scopus.com/pages/publications/84938631341

U2 - 10.1063/1.4927918

DO - 10.1063/1.4927918

M3 - 文章

AN - SCOPUS:84938631341

SN - 0021-9606

VL - 143

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 5

M1 - 051101

ER -

Communication: Tracking molecular structure deformation and relaxation in real time

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