Colorimetric magnetic microspheres as chemosensor for Cu2+ prepared from adamantane-modified rhodamine and β-cyclodextrin-modified Fe3O4@SiO2 via host-guest interaction

Yue Zhang; Wei Wang; Qiang Li; Qingbiao Yang; Yaoxian Li; Jianshi Du

doi:10.1016/j.talanta.2015.03.015

Colorimetric magnetic microspheres as chemosensor for Cu²⁺ prepared from adamantane-modified rhodamine and β-cyclodextrin-modified Fe₃O₄@SiO₂ via host-guest interaction

Yue Zhang
, Wei Wang
, Qiang Li
, Qingbiao Yang^*
, Yaoxian Li
, Jianshi Du

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

Adamantane-modified salicylrhodamine B and β-cyclodextrin-modified Fe₃O₄@SiO₂ were assemblied by host-guest interactions which induced novel inclusion complex magnetic nanoparticles (SFIC MNPs) colorimetric sensitive for Cu²⁺ being prepared. The MNPs exhibit a clear color change from colorless to pink selectively and sensitively with the addition of Cu²⁺ in the experiments of UV-visible spectra, and the detection limit measures up to 5.99×10^-6 M in solutions of CH₃CN-H₂O =1:10. The SFIC magnetic nanoparticles are superparamagnetic according to magnetic measurements and can be separated and collected easily with a commercial magnet in nine seconds. In addition, the microspheres have also showed good ability of separating for other ions from aqueous solutions due to a large number of hydroxyl groups on the surface.

Original language	English
Pages (from-to)	33-40
Number of pages	8
Journal	Talanta
Volume	141
DOIs	https://doi.org/10.1016/j.talanta.2015.03.015
State	Published - 2015
Externally published	Yes

Keywords

Chemosensor
Host-guest interaction
Magnetic microspheres
Rhodamine B
β-Cyclodextrin

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10.1016/j.talanta.2015.03.015

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@article{93401cb9bba949dc891cbce74b10351c,

title = "Colorimetric magnetic microspheres as chemosensor for Cu2+ prepared from adamantane-modified rhodamine and β-cyclodextrin-modified Fe3O4@SiO2 via host-guest interaction",

abstract = "Adamantane-modified salicylrhodamine B and β-cyclodextrin-modified Fe3O4@SiO2 were assemblied by host-guest interactions which induced novel inclusion complex magnetic nanoparticles (SFIC MNPs) colorimetric sensitive for Cu2+ being prepared. The MNPs exhibit a clear color change from colorless to pink selectively and sensitively with the addition of Cu2+ in the experiments of UV-visible spectra, and the detection limit measures up to 5.99×10-6 M in solutions of CH3CN-H2O =1:10. The SFIC magnetic nanoparticles are superparamagnetic according to magnetic measurements and can be separated and collected easily with a commercial magnet in nine seconds. In addition, the microspheres have also showed good ability of separating for other ions from aqueous solutions due to a large number of hydroxyl groups on the surface.",

keywords = "Chemosensor, Host-guest interaction, Magnetic microspheres, Rhodamine B, β-Cyclodextrin",

author = "Yue Zhang and Wei Wang and Qiang Li and Qingbiao Yang and Yaoxian Li and Jianshi Du",

year = "2015",

doi = "10.1016/j.talanta.2015.03.015",

language = "英语",

volume = "141",

pages = "33--40",

journal = "Talanta",

issn = "0039-9140",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Colorimetric magnetic microspheres as chemosensor for Cu2+ prepared from adamantane-modified rhodamine and β-cyclodextrin-modified Fe3O4@SiO2 via host-guest interaction

AU - Zhang, Yue

AU - Wang, Wei

AU - Li, Qiang

AU - Yang, Qingbiao

AU - Li, Yaoxian

AU - Du, Jianshi

PY - 2015

Y1 - 2015

N2 - Adamantane-modified salicylrhodamine B and β-cyclodextrin-modified Fe3O4@SiO2 were assemblied by host-guest interactions which induced novel inclusion complex magnetic nanoparticles (SFIC MNPs) colorimetric sensitive for Cu2+ being prepared. The MNPs exhibit a clear color change from colorless to pink selectively and sensitively with the addition of Cu2+ in the experiments of UV-visible spectra, and the detection limit measures up to 5.99×10-6 M in solutions of CH3CN-H2O =1:10. The SFIC magnetic nanoparticles are superparamagnetic according to magnetic measurements and can be separated and collected easily with a commercial magnet in nine seconds. In addition, the microspheres have also showed good ability of separating for other ions from aqueous solutions due to a large number of hydroxyl groups on the surface.

AB - Adamantane-modified salicylrhodamine B and β-cyclodextrin-modified Fe3O4@SiO2 were assemblied by host-guest interactions which induced novel inclusion complex magnetic nanoparticles (SFIC MNPs) colorimetric sensitive for Cu2+ being prepared. The MNPs exhibit a clear color change from colorless to pink selectively and sensitively with the addition of Cu2+ in the experiments of UV-visible spectra, and the detection limit measures up to 5.99×10-6 M in solutions of CH3CN-H2O =1:10. The SFIC magnetic nanoparticles are superparamagnetic according to magnetic measurements and can be separated and collected easily with a commercial magnet in nine seconds. In addition, the microspheres have also showed good ability of separating for other ions from aqueous solutions due to a large number of hydroxyl groups on the surface.

KW - Chemosensor

KW - Host-guest interaction

KW - Magnetic microspheres

KW - Rhodamine B

KW - β-Cyclodextrin

UR - https://www.scopus.com/pages/publications/84952669371

U2 - 10.1016/j.talanta.2015.03.015

DO - 10.1016/j.talanta.2015.03.015

M3 - 文章

C2 - 25966377

AN - SCOPUS:84952669371

SN - 0039-9140

VL - 141

SP - 33

EP - 40

JO - Talanta

JF - Talanta

ER -

Colorimetric magnetic microspheres as chemosensor for Cu²⁺ prepared from adamantane-modified rhodamine and β-cyclodextrin-modified Fe₃O₄@SiO₂ via host-guest interaction

Abstract

Keywords

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