Chiral anionic surfactants for asymmetric Mukaiyama aldol-type reaction in water

Hui Jing Li; Hong Yu Tian; Yong Jun Chen; Dong Wang; Chao Jun Li

doi:10.3184/030823403103173318

Chiral anionic surfactants for asymmetric Mukaiyama aldol-type reaction in water

Hui Jing Li
, Hong Yu Tian
, Yong Jun Chen
, Dong Wang^*
, Chao Jun Li

^*Corresponding author for this work

Chinese Academy of Sciences
Tulane University

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Sulfonate derivatives of chiral 1,1′-binaphthol were used as chiral anionic surfactants in asymmetric aldol-type reaction in water to give aldol adducts with moderate to good diastereo- and enantioselectivities; Ga(OTf)₃ and Cu(OTf)₂ were better than Sc(OTf)₃ as Lewis acid catalysts.

Original language	English
Pages (from-to)	153-156
Number of pages	4
Journal	Journal of Chemical Research - Part S
Issue number	3
DOIs	https://doi.org/10.3184/030823403103173318
State	Published - 1 Mar 2003
Externally published	Yes

Keywords

Asymmetric aldol-type reaction in water
Chiral surfactant
Lewis acid catalyst

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10.3184/030823403103173318

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title = "Chiral anionic surfactants for asymmetric Mukaiyama aldol-type reaction in water",

abstract = "Sulfonate derivatives of chiral 1,1′-binaphthol were used as chiral anionic surfactants in asymmetric aldol-type reaction in water to give aldol adducts with moderate to good diastereo- and enantioselectivities; Ga(OTf)3 and Cu(OTf)2 were better than Sc(OTf)3 as Lewis acid catalysts.",

keywords = "Asymmetric aldol-type reaction in water, Chiral surfactant, Lewis acid catalyst",

author = "Li, \{Hui Jing\} and Tian, \{Hong Yu\} and Chen, \{Yong Jun\} and Dong Wang and Li, \{Chao Jun\}",

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doi = "10.3184/030823403103173318",

language = "英语",

pages = "153--156",

journal = "Journal of Chemical Research - Part S",

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T1 - Chiral anionic surfactants for asymmetric Mukaiyama aldol-type reaction in water

AU - Li, Hui Jing

AU - Tian, Hong Yu

AU - Chen, Yong Jun

AU - Wang, Dong

AU - Li, Chao Jun

PY - 2003/3/1

Y1 - 2003/3/1

N2 - Sulfonate derivatives of chiral 1,1′-binaphthol were used as chiral anionic surfactants in asymmetric aldol-type reaction in water to give aldol adducts with moderate to good diastereo- and enantioselectivities; Ga(OTf)3 and Cu(OTf)2 were better than Sc(OTf)3 as Lewis acid catalysts.

AB - Sulfonate derivatives of chiral 1,1′-binaphthol were used as chiral anionic surfactants in asymmetric aldol-type reaction in water to give aldol adducts with moderate to good diastereo- and enantioselectivities; Ga(OTf)3 and Cu(OTf)2 were better than Sc(OTf)3 as Lewis acid catalysts.

KW - Asymmetric aldol-type reaction in water

KW - Chiral surfactant

KW - Lewis acid catalyst

UR - https://www.scopus.com/pages/publications/0038039250

U2 - 10.3184/030823403103173318

DO - 10.3184/030823403103173318

M3 - 文章

AN - SCOPUS:0038039250

SN - 0308-2342

SP - 153

EP - 156

JO - Journal of Chemical Research - Part S

JF - Journal of Chemical Research - Part S

IS - 3

ER -

Chiral anionic surfactants for asymmetric Mukaiyama aldol-type reaction in water

Abstract

Keywords

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