Chelation-Assisted C−N Cross-Coupling between Picolinamides and Aryl Boronic Acids under Nickel Catalysis

Zhen Xiao; Sihao Shu; Yi Lin; Qian Zhang; Peng Ren; Dong Li

doi:10.1002/ajoc.201800441

Chelation-Assisted C−N Cross-Coupling between Picolinamides and Aryl Boronic Acids under Nickel Catalysis

Zhen Xiao
, Sihao Shu
, Yi Lin
, Qian Zhang
, Peng Ren^*
, Dong Li

^*Corresponding author for this work

Hubei University of Technology
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A nickel-catalyzed C−N cross-coupling between picolinamides and aryl boronic acids was developed. It was promoted by the chelation assistance of picolinyl group without the use of ligands. The reaction proceeded under simple and mild conditions. It was applicable to various picolinamides as well as aryl boronic acids, providing the unsymmetrical N-aryl tertiary amides in moderate to good yields.

Original language	English
Pages (from-to)	2053-2056
Number of pages	4
Journal	Asian Journal of Organic Chemistry
Volume	7
Issue number	10
DOIs	https://doi.org/10.1002/ajoc.201800441
State	Published - Oct 2018
Externally published	Yes

Keywords

C−N bond formation
boronic acid
cross coupling
nickel catalysis
picolinamide

Access to Document

10.1002/ajoc.201800441

Cite this

@article{b2f2a8028c004c12b0196bb1c2f3ee46,

title = "Chelation-Assisted C−N Cross-Coupling between Picolinamides and Aryl Boronic Acids under Nickel Catalysis",

abstract = "A nickel-catalyzed C−N cross-coupling between picolinamides and aryl boronic acids was developed. It was promoted by the chelation assistance of picolinyl group without the use of ligands. The reaction proceeded under simple and mild conditions. It was applicable to various picolinamides as well as aryl boronic acids, providing the unsymmetrical N-aryl tertiary amides in moderate to good yields.",

keywords = "C−N bond formation, boronic acid, cross coupling, nickel catalysis, picolinamide",

author = "Zhen Xiao and Sihao Shu and Yi Lin and Qian Zhang and Peng Ren and Dong Li",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = oct,

doi = "10.1002/ajoc.201800441",

language = "英语",

volume = "7",

pages = "2053--2056",

journal = "Asian Journal of Organic Chemistry",

issn = "2193-5807",

publisher = "John Wiley and Sons Inc",

number = "10",

}

TY - JOUR

T1 - Chelation-Assisted C−N Cross-Coupling between Picolinamides and Aryl Boronic Acids under Nickel Catalysis

AU - Xiao, Zhen

AU - Shu, Sihao

AU - Lin, Yi

AU - Zhang, Qian

AU - Ren, Peng

AU - Li, Dong

PY - 2018/10

Y1 - 2018/10

N2 - A nickel-catalyzed C−N cross-coupling between picolinamides and aryl boronic acids was developed. It was promoted by the chelation assistance of picolinyl group without the use of ligands. The reaction proceeded under simple and mild conditions. It was applicable to various picolinamides as well as aryl boronic acids, providing the unsymmetrical N-aryl tertiary amides in moderate to good yields.

AB - A nickel-catalyzed C−N cross-coupling between picolinamides and aryl boronic acids was developed. It was promoted by the chelation assistance of picolinyl group without the use of ligands. The reaction proceeded under simple and mild conditions. It was applicable to various picolinamides as well as aryl boronic acids, providing the unsymmetrical N-aryl tertiary amides in moderate to good yields.

KW - C−N bond formation

KW - boronic acid

KW - cross coupling

KW - nickel catalysis

KW - picolinamide

UR - https://www.scopus.com/pages/publications/85053372791

U2 - 10.1002/ajoc.201800441

DO - 10.1002/ajoc.201800441

M3 - 文章

AN - SCOPUS:85053372791

SN - 2193-5807

VL - 7

SP - 2053

EP - 2056

JO - Asian Journal of Organic Chemistry

JF - Asian Journal of Organic Chemistry

IS - 10

ER -

Chelation-Assisted C−N Cross-Coupling between Picolinamides and Aryl Boronic Acids under Nickel Catalysis

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this