Characterization and coating properties of silsesquioxanes derived from the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane

Lijiang Hu; Xingwen Zhang; Hong You; Yan Liu; Hao Zhang; Dezhi Sun

doi:10.1023/B:JMSC.0000013893.58417.7e

Characterization and coating properties of silsesquioxanes derived from the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane

Lijiang Hu^*
, Xingwen Zhang
, Hong You
, Yan Liu
, Hao Zhang
, Dezhi Sun

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Siisesquioxanes (SSO) were synthesized by the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane (GPMS). Their structure was characterized by FTIR and NMR (¹H, ¹³C, ²⁹Si), and the molar mass distribution was determined by UV-MALDI-TOF MS. Films were synthesized by adding the stoichiometric amount of ethylenediamine to SSO solutions in ethanol, dip-coating over glass substrates, and curing using an appropriate thermal cycle. The transmittance of the films was measured by UV-VIS-NIR scanning spectrophotometer (SSP); hardness and modulus were determined with the continuous stiffness measurement (CSM) technique of an instrumented-indentation testing (IIT) device. The effect of the substrate on the coating system was analyzed.

Original language	English
Pages (from-to)	1331-1335
Number of pages	5
Journal	Journal of Materials Science
Volume	39
Issue number	4
DOIs	https://doi.org/10.1023/B:JMSC.0000013893.58417.7e
State	Published - 15 Feb 2004

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title = "Characterization and coating properties of silsesquioxanes derived from the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane",

abstract = "Siisesquioxanes (SSO) were synthesized by the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane (GPMS). Their structure was characterized by FTIR and NMR (1H, 13C, 29Si), and the molar mass distribution was determined by UV-MALDI-TOF MS. Films were synthesized by adding the stoichiometric amount of ethylenediamine to SSO solutions in ethanol, dip-coating over glass substrates, and curing using an appropriate thermal cycle. The transmittance of the films was measured by UV-VIS-NIR scanning spectrophotometer (SSP); hardness and modulus were determined with the continuous stiffness measurement (CSM) technique of an instrumented-indentation testing (IIT) device. The effect of the substrate on the coating system was analyzed.",

author = "Lijiang Hu and Xingwen Zhang and Hong You and Yan Liu and Hao Zhang and Dezhi Sun",

year = "2004",

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doi = "10.1023/B:JMSC.0000013893.58417.7e",

language = "英语",

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pages = "1331--1335",

journal = "Journal of Materials Science",

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TY - JOUR

T1 - Characterization and coating properties of silsesquioxanes derived from the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane

AU - Hu, Lijiang

AU - Zhang, Xingwen

AU - You, Hong

AU - Liu, Yan

AU - Zhang, Hao

AU - Sun, Dezhi

PY - 2004/2/15

Y1 - 2004/2/15

N2 - Siisesquioxanes (SSO) were synthesized by the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane (GPMS). Their structure was characterized by FTIR and NMR (1H, 13C, 29Si), and the molar mass distribution was determined by UV-MALDI-TOF MS. Films were synthesized by adding the stoichiometric amount of ethylenediamine to SSO solutions in ethanol, dip-coating over glass substrates, and curing using an appropriate thermal cycle. The transmittance of the films was measured by UV-VIS-NIR scanning spectrophotometer (SSP); hardness and modulus were determined with the continuous stiffness measurement (CSM) technique of an instrumented-indentation testing (IIT) device. The effect of the substrate on the coating system was analyzed.

AB - Siisesquioxanes (SSO) were synthesized by the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane (GPMS). Their structure was characterized by FTIR and NMR (1H, 13C, 29Si), and the molar mass distribution was determined by UV-MALDI-TOF MS. Films were synthesized by adding the stoichiometric amount of ethylenediamine to SSO solutions in ethanol, dip-coating over glass substrates, and curing using an appropriate thermal cycle. The transmittance of the films was measured by UV-VIS-NIR scanning spectrophotometer (SSP); hardness and modulus were determined with the continuous stiffness measurement (CSM) technique of an instrumented-indentation testing (IIT) device. The effect of the substrate on the coating system was analyzed.

UR - https://www.scopus.com/pages/publications/1442311682

U2 - 10.1023/B:JMSC.0000013893.58417.7e

DO - 10.1023/B:JMSC.0000013893.58417.7e

M3 - 文章

AN - SCOPUS:1442311682

SN - 0022-2461

VL - 39

SP - 1331

EP - 1335

JO - Journal of Materials Science

JF - Journal of Materials Science

IS - 4

ER -

Characterization and coating properties of silsesquioxanes derived from the hydrolytic condensation of (3-glycidoxypropyl)trimethoxysilane

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