Characteristics of Sb Doping in Potassium Tantalate Niobate Single Crystals

Yuwen Qiao; Minghui Cao; Xing Wen; Jinyu Ruan; Qingyang Shan; Mingxuan Liu; Ming Qiu; Yu Wang; Xiangda Meng; Peng Tan; Hao Tian

doi:10.1021/acs.cgd.4c01093

Characteristics of Sb Doping in Potassium Tantalate Niobate Single Crystals

Yuwen Qiao
, Minghui Cao
, Xing Wen
, Jinyu Ruan
, Qingyang Shan
, Mingxuan Liu
, Ming Qiu
, Yu Wang
, Xiangda Meng
, Peng Tan^*
, Hao Tian

^*Corresponding author for this work

School of Physics, Harbin Institute of Technology
Heilongjiang Provincial Key Laboratory of Advanced Quantum Functional Materials and Sensor Devices

Research output: Contribution to journal › Article › peer-review

Abstract

Sb doping is an effective method to modify the properties of perovskite ferroelectrics and improve material characteristics. However, the specific effects of Sb doping in perovskite ferroelectrics remain unclear. In this paper, we investigate the properties of Sb-doped potassium tantalum niobate single crystals. Using an improved top-seeded solution growth method, we successfully grew Sb-doped KTa_xNb_1-xO₃ (Sb:KTN) single crystals. We examined the occupation and valence states of the doped Sb ions and their effects on the crystal structure. Additionally, we characterized the dielectric, ferroelectric, piezoelectric, and optical properties of the Sb:KTN single crystal. This study highlights the impact of Sb doping on the structure and properties of KTN single crystals, providing a foundation for designing and applying lead-free perovskite ferroelectrics.

Original language	English
Journal	Crystal Growth and Design
DOIs	https://doi.org/10.1021/acs.cgd.4c01093
State	Accepted/In press - 2024
Externally published	Yes

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10.1021/acs.cgd.4c01093

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title = "Characteristics of Sb Doping in Potassium Tantalate Niobate Single Crystals",

abstract = "Sb doping is an effective method to modify the properties of perovskite ferroelectrics and improve material characteristics. However, the specific effects of Sb doping in perovskite ferroelectrics remain unclear. In this paper, we investigate the properties of Sb-doped potassium tantalum niobate single crystals. Using an improved top-seeded solution growth method, we successfully grew Sb-doped KTaxNb1-xO3 (Sb:KTN) single crystals. We examined the occupation and valence states of the doped Sb ions and their effects on the crystal structure. Additionally, we characterized the dielectric, ferroelectric, piezoelectric, and optical properties of the Sb:KTN single crystal. This study highlights the impact of Sb doping on the structure and properties of KTN single crystals, providing a foundation for designing and applying lead-free perovskite ferroelectrics.",

author = "Yuwen Qiao and Minghui Cao and Xing Wen and Jinyu Ruan and Qingyang Shan and Mingxuan Liu and Ming Qiu and Yu Wang and Xiangda Meng and Peng Tan and Hao Tian",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society.",

year = "2024",

doi = "10.1021/acs.cgd.4c01093",

language = "英语",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

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TY - JOUR

T1 - Characteristics of Sb Doping in Potassium Tantalate Niobate Single Crystals

AU - Qiao, Yuwen

AU - Cao, Minghui

AU - Wen, Xing

AU - Ruan, Jinyu

AU - Shan, Qingyang

AU - Liu, Mingxuan

AU - Qiu, Ming

AU - Wang, Yu

AU - Meng, Xiangda

AU - Tan, Peng

AU - Tian, Hao

PY - 2024

Y1 - 2024

N2 - Sb doping is an effective method to modify the properties of perovskite ferroelectrics and improve material characteristics. However, the specific effects of Sb doping in perovskite ferroelectrics remain unclear. In this paper, we investigate the properties of Sb-doped potassium tantalum niobate single crystals. Using an improved top-seeded solution growth method, we successfully grew Sb-doped KTaxNb1-xO3 (Sb:KTN) single crystals. We examined the occupation and valence states of the doped Sb ions and their effects on the crystal structure. Additionally, we characterized the dielectric, ferroelectric, piezoelectric, and optical properties of the Sb:KTN single crystal. This study highlights the impact of Sb doping on the structure and properties of KTN single crystals, providing a foundation for designing and applying lead-free perovskite ferroelectrics.

AB - Sb doping is an effective method to modify the properties of perovskite ferroelectrics and improve material characteristics. However, the specific effects of Sb doping in perovskite ferroelectrics remain unclear. In this paper, we investigate the properties of Sb-doped potassium tantalum niobate single crystals. Using an improved top-seeded solution growth method, we successfully grew Sb-doped KTaxNb1-xO3 (Sb:KTN) single crystals. We examined the occupation and valence states of the doped Sb ions and their effects on the crystal structure. Additionally, we characterized the dielectric, ferroelectric, piezoelectric, and optical properties of the Sb:KTN single crystal. This study highlights the impact of Sb doping on the structure and properties of KTN single crystals, providing a foundation for designing and applying lead-free perovskite ferroelectrics.

UR - https://www.scopus.com/pages/publications/85206154084

U2 - 10.1021/acs.cgd.4c01093

DO - 10.1021/acs.cgd.4c01093

M3 - 文章

AN - SCOPUS:85206154084

SN - 1528-7483

JO - Crystal Growth and Design

JF - Crystal Growth and Design

ER -

Characteristics of Sb Doping in Potassium Tantalate Niobate Single Crystals

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