Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates

Zhiwei Liu; Wei Wang; Jinkui Tang; Weiqi Li; Weiye Yin; Xikui Fang

doi:10.1039/c9cc02854d

Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates

Zhiwei Liu
, Wei Wang
, Jinkui Tang
, Weiqi Li
, Weiye Yin
, Xikui Fang^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
CAS - Fujian Institute of Research on the Structure of Matter
CAS - Changchun Institute of Applied Chemistry
School of Physics, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

Altering the organic spacers in hybrid complexes of polyoxotungstates and long-chain α,ω-alkyldiphosphonates (Ln), by a single CH₂ group (e.g.L6vs.L5), can steer the self-assembly processes into different paths. Even homologous hybrids of L5 and L4 have seen the spin ground states switch from S = 0 to S = 9 upon shortening the chain length (L5vs.L4).

Original language	English
Pages (from-to)	6547-6550
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	46
DOIs	https://doi.org/10.1039/c9cc02854d
State	Published - 2019
Externally published	Yes

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title = "Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates",

abstract = "Altering the organic spacers in hybrid complexes of polyoxotungstates and long-chain α,ω-alkyldiphosphonates (Ln), by a single CH2 group (e.g.L6vs.L5), can steer the self-assembly processes into different paths. Even homologous hybrids of L5 and L4 have seen the spin ground states switch from S = 0 to S = 9 upon shortening the chain length (L5vs.L4).",

author = "Zhiwei Liu and Wei Wang and Jinkui Tang and Weiqi Li and Weiye Yin and Xikui Fang",

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T1 - Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates

AU - Liu, Zhiwei

AU - Wang, Wei

AU - Tang, Jinkui

AU - Li, Weiqi

AU - Yin, Weiye

AU - Fang, Xikui

N1 - Publisher Copyright: © The Royal Society of Chemistry 2019.

PY - 2019

Y1 - 2019

N2 - Altering the organic spacers in hybrid complexes of polyoxotungstates and long-chain α,ω-alkyldiphosphonates (Ln), by a single CH2 group (e.g.L6vs.L5), can steer the self-assembly processes into different paths. Even homologous hybrids of L5 and L4 have seen the spin ground states switch from S = 0 to S = 9 upon shortening the chain length (L5vs.L4).

AB - Altering the organic spacers in hybrid complexes of polyoxotungstates and long-chain α,ω-alkyldiphosphonates (Ln), by a single CH2 group (e.g.L6vs.L5), can steer the self-assembly processes into different paths. Even homologous hybrids of L5 and L4 have seen the spin ground states switch from S = 0 to S = 9 upon shortening the chain length (L5vs.L4).

UR - https://www.scopus.com/pages/publications/85066844731

U2 - 10.1039/c9cc02854d

DO - 10.1039/c9cc02854d

M3 - 文章

C2 - 31106799

AN - SCOPUS:85066844731

SN - 1359-7345

VL - 55

SP - 6547

EP - 6550

JO - Chemical Communications

JF - Chemical Communications

IS - 46

ER -

Chain length effect in the functionalization of polyoxometalates with α,ω-alkyldiphosphonates

Abstract

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