Catena-Poly[[aqua-dioxidouranium(VI)]-μ3-4, 4′-oxydibenzoato]

Wei Wang; Dao Jun Zhang; Yong Fan; Tian You Song; Ping Zhang

doi:10.1107/S1600536810010639

Catena-Poly[[aqua-dioxidouranium(VI)]-μ₃-4, 4′-oxydibenzoato]

Wei Wang
, Dao Jun Zhang
, Yong Fan
, Tian You Song
, Ping Zhang^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

The title compound, [UO₂(C₁₄H₈O ₅)(H₂O)]_n , is a polymeric UO₂ complex bridged by 4,4′-oxydibenzoate ligands. One carboxyl-ate group of the bridging ligand chelates a uranyl cation while the other carboxyl-ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central U^VI atom is seven-coordin-ated in a distorted UO₇ penta-gonal-bipyramidal geometry. In the crystal structure, O - H⋯O hydrogen bonding links the polymeric chains into a three-dimensional supra-molecular framework. Within the bridging ligand, the two benzene rings are oriented at a dihedral angle of 59.0 (2)°.

Original language	English
Pages (from-to)	m462
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	4
DOIs	https://doi.org/10.1107/S1600536810010639
State	Published - 2010
Externally published	Yes

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@article{031413f8469b4502b163a86313c5349f,

title = "Catena-Poly[[aqua-dioxidouranium(VI)]-μ3-4, 4′-oxydibenzoato]",

abstract = "The title compound, [UO2(C14H8O 5)(H2O)]n , is a polymeric UO2 complex bridged by 4,4′-oxydibenzoate ligands. One carboxyl-ate group of the bridging ligand chelates a uranyl cation while the other carboxyl-ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central UVI atom is seven-coordin-ated in a distorted UO7 penta-gonal-bipyramidal geometry. In the crystal structure, O - H⋯O hydrogen bonding links the polymeric chains into a three-dimensional supra-molecular framework. Within the bridging ligand, the two benzene rings are oriented at a dihedral angle of 59.0 (2)°.",

author = "Wei Wang and Zhang, \{Dao Jun\} and Yong Fan and Song, \{Tian You\} and Ping Zhang",

year = "2010",

doi = "10.1107/S1600536810010639",

language = "英语",

volume = "66",

pages = "m462",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "4",

}

TY - JOUR

T1 - Catena-Poly[[aqua-dioxidouranium(VI)]-μ3-4, 4′-oxydibenzoato]

AU - Wang, Wei

AU - Zhang, Dao Jun

AU - Fan, Yong

AU - Song, Tian You

AU - Zhang, Ping

PY - 2010

Y1 - 2010

N2 - The title compound, [UO2(C14H8O 5)(H2O)]n , is a polymeric UO2 complex bridged by 4,4′-oxydibenzoate ligands. One carboxyl-ate group of the bridging ligand chelates a uranyl cation while the other carboxyl-ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central UVI atom is seven-coordin-ated in a distorted UO7 penta-gonal-bipyramidal geometry. In the crystal structure, O - H⋯O hydrogen bonding links the polymeric chains into a three-dimensional supra-molecular framework. Within the bridging ligand, the two benzene rings are oriented at a dihedral angle of 59.0 (2)°.

AB - The title compound, [UO2(C14H8O 5)(H2O)]n , is a polymeric UO2 complex bridged by 4,4′-oxydibenzoate ligands. One carboxyl-ate group of the bridging ligand chelates a uranyl cation while the other carboxyl-ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central UVI atom is seven-coordin-ated in a distorted UO7 penta-gonal-bipyramidal geometry. In the crystal structure, O - H⋯O hydrogen bonding links the polymeric chains into a three-dimensional supra-molecular framework. Within the bridging ligand, the two benzene rings are oriented at a dihedral angle of 59.0 (2)°.

UR - https://www.scopus.com/pages/publications/77951227975

U2 - 10.1107/S1600536810010639

DO - 10.1107/S1600536810010639

M3 - 文章

AN - SCOPUS:77951227975

SN - 1600-5368

VL - 66

SP - m462

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 4

ER -

Catena-Poly[[aqua-dioxidouranium(VI)]-μ₃-4, 4′-oxydibenzoato]

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