Catena-Poly[[(4-aminobenzoato)aqua-silver(I)]- μ-hexa-methyl- enetetramine]

Jia Jun Han; Tian Yun Zhang; Lin Geng

doi:10.1107/S1600536809055044

Catena-Poly[[(4-aminobenzoato)aqua-silver(I)]- μ-hexa-methyl- enetetramine]

Jia Jun Han^*
, Tian Yun Zhang
, Lin Geng

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

In the title coordination polymer, [Ag(C₇H₆NO ₂)(C₆H₁₂N₄)(H₂O)] n , the Ag^I ion is five-coordinated by two carboxyl-ate O atoms from one 4-amino-benzoate anion (L), two N atoms from two different hexa-methyl- enetetramine (hmt) ligands, and one water O atom in a distorted square-pyramidal geometry. The metal atom lies on a mirror plane and the L anion, hmt ligand and water molecule all lie across crystallographic mirror planes. Each hmt ligand bridges two neighboring Ag^I ions, resulting in the formation of a chain structure along the b axis. The chains are linked into a three-dimensional framework by N - H⋯O and O - H⋯O hydrogen bonds.

Original language	English
Pages (from-to)	m111
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	66
Issue number	2
DOIs	https://doi.org/10.1107/S1600536809055044
State	Published - 2010
Externally published	Yes

Keywords

Data-to-parameter ratio = 12.7.
Mean σ(C-C) = 0.002 Å
R factor = 0.019
Single-crystal X-ray study
T = 293 K
WR factor = 0.048

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@article{6d0b750179d44ea8a1c9ee4f0015ed55,

title = "Catena-Poly[[(4-aminobenzoato)aqua-silver(I)]- μ-hexa-methyl- enetetramine]",

abstract = "In the title coordination polymer, [Ag(C7H6NO 2)(C6H12N4)(H2O)] n , the AgI ion is five-coordinated by two carboxyl-ate O atoms from one 4-amino-benzoate anion (L), two N atoms from two different hexa-methyl- enetetramine (hmt) ligands, and one water O atom in a distorted square-pyramidal geometry. The metal atom lies on a mirror plane and the L anion, hmt ligand and water molecule all lie across crystallographic mirror planes. Each hmt ligand bridges two neighboring AgI ions, resulting in the formation of a chain structure along the b axis. The chains are linked into a three-dimensional framework by N - H⋯O and O - H⋯O hydrogen bonds.",

keywords = "Data-to-parameter ratio = 12.7., Mean σ(C-C) = 0.002 {\AA}, R factor = 0.019, Single-crystal X-ray study, T = 293 K, WR factor = 0.048",

author = "Han, \{Jia Jun\} and Zhang, \{Tian Yun\} and Lin Geng",

year = "2010",

doi = "10.1107/S1600536809055044",

language = "英语",

volume = "66",

pages = "m111",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "2",

}

TY - JOUR

T1 - Catena-Poly[[(4-aminobenzoato)aqua-silver(I)]- μ-hexa-methyl- enetetramine]

AU - Han, Jia Jun

AU - Zhang, Tian Yun

AU - Geng, Lin

PY - 2010

Y1 - 2010

N2 - In the title coordination polymer, [Ag(C7H6NO 2)(C6H12N4)(H2O)] n , the AgI ion is five-coordinated by two carboxyl-ate O atoms from one 4-amino-benzoate anion (L), two N atoms from two different hexa-methyl- enetetramine (hmt) ligands, and one water O atom in a distorted square-pyramidal geometry. The metal atom lies on a mirror plane and the L anion, hmt ligand and water molecule all lie across crystallographic mirror planes. Each hmt ligand bridges two neighboring AgI ions, resulting in the formation of a chain structure along the b axis. The chains are linked into a three-dimensional framework by N - H⋯O and O - H⋯O hydrogen bonds.

AB - In the title coordination polymer, [Ag(C7H6NO 2)(C6H12N4)(H2O)] n , the AgI ion is five-coordinated by two carboxyl-ate O atoms from one 4-amino-benzoate anion (L), two N atoms from two different hexa-methyl- enetetramine (hmt) ligands, and one water O atom in a distorted square-pyramidal geometry. The metal atom lies on a mirror plane and the L anion, hmt ligand and water molecule all lie across crystallographic mirror planes. Each hmt ligand bridges two neighboring AgI ions, resulting in the formation of a chain structure along the b axis. The chains are linked into a three-dimensional framework by N - H⋯O and O - H⋯O hydrogen bonds.

KW - Data-to-parameter ratio = 12.7.

KW - Mean σ(C-C) = 0.002 Å

KW - R factor = 0.019

KW - Single-crystal X-ray study

KW - T = 293 K

KW - WR factor = 0.048

UR - https://www.scopus.com/pages/publications/76749134761

U2 - 10.1107/S1600536809055044

DO - 10.1107/S1600536809055044

M3 - 文章

AN - SCOPUS:76749134761

SN - 1600-5368

VL - 66

SP - m111

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 2

ER -

Catena-Poly[[(4-aminobenzoato)aqua-silver(I)]- μ-hexa-methyl- enetetramine]

Abstract

Keywords

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