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Catalytic oxidation of chlorobenzenes using ozone over CNT-based composites

  • Zhejiang University
  • Chinese University of Hong Kong

Research output: Chapter in Book/Report/Conference proceedingConference contributionpeer-review

Abstract

Catalytic oxidation of chlorobenzenes (CBs) over carbon nanotubes (CNTs) supported manganese oxide and copper oxide (MnOx and CuOx) at different temperature are studied. Accordingly, a CB complete oxidation of >95 % was achieved over MnOx/CNTs and CuOx/CNTs at 80 °C and 240 °C, respectively. The stability and resistance to chlorine poisoning of catalysts were evaluated. Moreover, chlorine substituents were found to have a negative influence on ozone promotion because of their electrophilicity. In addition, the reaction mechanism of CB catalytic oxidation with ozone was described on the basis of kinetic study.

Original languageEnglish
Title of host publicationIEEE-NANO 2015 - 15th International Conference on Nanotechnology
PublisherInstitute of Electrical and Electronics Engineers Inc.
Pages229-233
Number of pages5
ISBN (Electronic)9781467381550
DOIs
StatePublished - 2015
Externally publishedYes
Event15th IEEE International Conference on Nanotechnology, IEEE-NANO 2015 - Rome, Italy
Duration: 27 Jul 201530 Jul 2015

Publication series

NameIEEE-NANO 2015 - 15th International Conference on Nanotechnology

Conference

Conference15th IEEE International Conference on Nanotechnology, IEEE-NANO 2015
Country/TerritoryItaly
CityRome
Period27/07/1530/07/15

Keywords

  • carbon nanotube
  • catalytic oxidation
  • copper oxide
  • manganese oxide
  • ozone

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