Catalytic epoxidation of styrene over copper hydroxyphosphate Cu2(OH)PO4

Xiangju Meng; Kaifeng Lin; Jianmin Sun; Miao Yang; Dazhen Jiang; Feng Shou Xiao

doi:10.1023/A:1009051104167

Catalytic epoxidation of styrene over copper hydroxyphosphate Cu₂(OH)PO₄

Xiangju Meng
, Kaifeng Lin
, Jianmin Sun
, Miao Yang
, Dazhen Jiang
, Feng Shou Xiao^*

^*Corresponding author for this work

Jilin University

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

Catalytic epoxidation of styrene with hydrogen peroxide over copper hydroxyphosphate Cu₂(OH)PO₄ was studied, Catalytic data shows that the catalyst Cu₂(OH)PO₄ is very active, and the main products are styrene epoxide and benzaldehyde, particlularly giving high selectivity for styrene epoxide. In contrast, over TS-1 a large amount of phenylacetaldehyde product is formed. Some important factors associated with the catalytic activity and selectivity are investigated extensively.

Original language	English
Pages (from-to)	241-244
Number of pages	4
Journal	Catalysis Letters
Volume	71
Issue number	3-4
DOIs	https://doi.org/10.1023/A:1009051104167
State	Published - Feb 2001
Externally published	Yes

Keywords

Copper hydroxyphosphate
Hydrogen peroxide
Styrene epoxidation

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title = "Catalytic epoxidation of styrene over copper hydroxyphosphate Cu2(OH)PO4",

abstract = "Catalytic epoxidation of styrene with hydrogen peroxide over copper hydroxyphosphate Cu2(OH)PO4 was studied, Catalytic data shows that the catalyst Cu2(OH)PO4 is very active, and the main products are styrene epoxide and benzaldehyde, particlularly giving high selectivity for styrene epoxide. In contrast, over TS-1 a large amount of phenylacetaldehyde product is formed. Some important factors associated with the catalytic activity and selectivity are investigated extensively.",

keywords = "Copper hydroxyphosphate, Hydrogen peroxide, Styrene epoxidation",

author = "Xiangju Meng and Kaifeng Lin and Jianmin Sun and Miao Yang and Dazhen Jiang and Xiao, \{Feng Shou\}",

year = "2001",

month = feb,

doi = "10.1023/A:1009051104167",

language = "英语",

volume = "71",

pages = "241--244",

journal = "Catalysis Letters",

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publisher = "Kluwer Academic Publishers",

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TY - JOUR

T1 - Catalytic epoxidation of styrene over copper hydroxyphosphate Cu2(OH)PO4

AU - Meng, Xiangju

AU - Lin, Kaifeng

AU - Sun, Jianmin

AU - Yang, Miao

AU - Jiang, Dazhen

AU - Xiao, Feng Shou

PY - 2001/2

Y1 - 2001/2

N2 - Catalytic epoxidation of styrene with hydrogen peroxide over copper hydroxyphosphate Cu2(OH)PO4 was studied, Catalytic data shows that the catalyst Cu2(OH)PO4 is very active, and the main products are styrene epoxide and benzaldehyde, particlularly giving high selectivity for styrene epoxide. In contrast, over TS-1 a large amount of phenylacetaldehyde product is formed. Some important factors associated with the catalytic activity and selectivity are investigated extensively.

AB - Catalytic epoxidation of styrene with hydrogen peroxide over copper hydroxyphosphate Cu2(OH)PO4 was studied, Catalytic data shows that the catalyst Cu2(OH)PO4 is very active, and the main products are styrene epoxide and benzaldehyde, particlularly giving high selectivity for styrene epoxide. In contrast, over TS-1 a large amount of phenylacetaldehyde product is formed. Some important factors associated with the catalytic activity and selectivity are investigated extensively.

KW - Copper hydroxyphosphate

KW - Hydrogen peroxide

KW - Styrene epoxidation

UR - https://www.scopus.com/pages/publications/0035262851

U2 - 10.1023/A:1009051104167

DO - 10.1023/A:1009051104167

M3 - 文章

AN - SCOPUS:0035262851

SN - 1011-372X

VL - 71

SP - 241

EP - 244

JO - Catalysis Letters

JF - Catalysis Letters

IS - 3-4

ER -

Catalytic epoxidation of styrene over copper hydroxyphosphate Cu₂(OH)PO₄

Abstract

Keywords

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