Calculations of circular intensity differences in electric-field-induced second harmonic generation

Dan Jonsson; Yi Luo; Kenneth Ruud; Patrick Norman; Hans Ågren

doi:10.1016/S0009-2614(98)00301-7

Calculations of circular intensity differences in electric-field-induced second harmonic generation

Dan Jonsson^*
, Yi Luo
, Kenneth Ruud
, Patrick Norman
, Hans Ågren

^*Corresponding author for this work

Linköping University
University of Oslo

Research output: Contribution to journal › Article › peer-review

5 Scopus citations

Abstract

Ab initio calculations of electric-field induced second-harmonic generation for chiral molecules are presented. The calculations employ cubic response theory and take into account electric-dipole, electric-quadrupole and magnetic-dipole interactions, which result in an intensity dependence on the helicity of the light. The circular intensity difference is calculated for the chiral molecules twisted ethylene, trans-1,2-dimethylcyclopropane and methyloxirane. The calculated circular intensity differences are small - being of the order of 10^-4-10^-3 - but such electric-field induced second harmonic generation intensity dependencies should be experimentally detectable.

Original language	English
Pages (from-to)	371-376
Number of pages	6
Journal	Chemical Physics Letters
Volume	288
Issue number	2-4
DOIs	https://doi.org/10.1016/S0009-2614(98)00301-7
State	Published - 22 May 1998
Externally published	Yes

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title = "Calculations of circular intensity differences in electric-field-induced second harmonic generation",

abstract = "Ab initio calculations of electric-field induced second-harmonic generation for chiral molecules are presented. The calculations employ cubic response theory and take into account electric-dipole, electric-quadrupole and magnetic-dipole interactions, which result in an intensity dependence on the helicity of the light. The circular intensity difference is calculated for the chiral molecules twisted ethylene, trans-1,2-dimethylcyclopropane and methyloxirane. The calculated circular intensity differences are small - being of the order of 10-4-10-3 - but such electric-field induced second harmonic generation intensity dependencies should be experimentally detectable.",

author = "Dan Jonsson and Yi Luo and Kenneth Ruud and Patrick Norman and Hans {\AA}gren",

year = "1998",

month = may,

day = "22",

doi = "10.1016/S0009-2614(98)00301-7",

language = "英语",

volume = "288",

pages = "371--376",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "2-4",

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TY - JOUR

T1 - Calculations of circular intensity differences in electric-field-induced second harmonic generation

AU - Jonsson, Dan

AU - Luo, Yi

AU - Ruud, Kenneth

AU - Norman, Patrick

AU - Ågren, Hans

PY - 1998/5/22

Y1 - 1998/5/22

N2 - Ab initio calculations of electric-field induced second-harmonic generation for chiral molecules are presented. The calculations employ cubic response theory and take into account electric-dipole, electric-quadrupole and magnetic-dipole interactions, which result in an intensity dependence on the helicity of the light. The circular intensity difference is calculated for the chiral molecules twisted ethylene, trans-1,2-dimethylcyclopropane and methyloxirane. The calculated circular intensity differences are small - being of the order of 10-4-10-3 - but such electric-field induced second harmonic generation intensity dependencies should be experimentally detectable.

AB - Ab initio calculations of electric-field induced second-harmonic generation for chiral molecules are presented. The calculations employ cubic response theory and take into account electric-dipole, electric-quadrupole and magnetic-dipole interactions, which result in an intensity dependence on the helicity of the light. The circular intensity difference is calculated for the chiral molecules twisted ethylene, trans-1,2-dimethylcyclopropane and methyloxirane. The calculated circular intensity differences are small - being of the order of 10-4-10-3 - but such electric-field induced second harmonic generation intensity dependencies should be experimentally detectable.

UR - https://www.scopus.com/pages/publications/0032557320

U2 - 10.1016/S0009-2614(98)00301-7

DO - 10.1016/S0009-2614(98)00301-7

M3 - 文章

AN - SCOPUS:0032557320

SN - 0009-2614

VL - 288

SP - 371

EP - 376

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 2-4

ER -

Calculations of circular intensity differences in electric-field-induced second harmonic generation

Abstract

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