Boosting photocatalytic chlorophenols remediation with addition of sulfite and mechanism investigation by in-situ DRIFTs

Sulfite is recently found to be promising in enhancing photocatalytic pollutants degradation, which is a byproduct from flue gas desulfuration process. Herein, 4-chlorophenol (4-CP) photodegradation was systematically investigated in a sulfite mediated system with g-C₃N₄ as photocatalyst. The degradation efficacy was improved by about 3 times with addition of 25 mM Na₂SO₃. The dominant responsible reactive oxygen species for chlorophenols remediation in the presence of sulfite included O₂^·−, SO₃^·−, and SO₄^·− as confirmed by radical quenching experiments and electron spin resonances technology. In-situ DRIFTs results indicated the improved cleavage of C[sbnd]Cl and C[sbnd]H bonds with the simultaneous formation of C[dbnd]O and [sbnd]C[dbnd]C[sbnd] bonds when bisulfite was added. Degradation intermediates such as 4-chlorocatechol, hydroquinone, and muconic acid were detected by HPLC-MS. Furthermore, the photodegradation mechanisms of 4-CP were tentatively discussed . Other chlorophenols (phenol, 2-CP, 2,4-DCP, and their mixture) were also efficiently removed in the system, suggesting that sulfite could be universally applied in photocatalytic wastewater purification.