Boosting electron transport process over multiple channels induced by S-doped carbon and Fe₇S₈ NPs interface toward high-efficiency antibiotics removal

The enhancement of electron transport process on multiple channels of C−Fe and C−S−Fe bonds between dual-reaction centres was investigated for stimulating the antibiotics degradation in Fenton-like processes. Herein, multiple channels structure of sulfur-doped carbon coupled Fe₇S₈ cluster through C−Fe bond and C−S−Fe bond was constructed through density functional theory (DFT), and S-doped carbon framework coated Fe₇S₈ nanoparticles (Fe₇S₈/SC) Fenton-like catalyst was prepared through hydrothermal and subsequent sulfuration process. The DFT calculations revealed that electrons are thermodynamically transferred from carbon to iron along both C−Fe and C−S−Fe bonds. The optimized Fe₇S₈/SC catalyst exhibited desirable catalytic property for Fenton-like degradation for various antibiotics, the removal of amoxicillin, norfloxacin, and tetracycline hydrochloride reach 98.9%, 97.8%, and 99.3% respectively within 40 min under neutral pH, and catalyst also demonstrated excellent cycle stability after five runs. The excellent degradation effect of antibiotics by Fenton-like catalyst was attributed to the intensified electron transport process by multiple electron transfer channels between dual reaction centres, making [tbnd]Fe^II easier to regenerate. This study spreads a new route for the enhancement of electron transport process in Fenton-like catalysts by constructing multiple channels.