Black phosphorus-modified sulfurized polyacrylonitrile with high C-rate and cycling performance in ether-based electrolyte for lithium sulfur batteries

Shaobo Ma; Yang Wang; Chuankai Fu; Yulin Ma; Yunzhi Gao; Geping Yin; Pengjian Zuo

doi:10.1039/d0cc04901h

Black phosphorus-modified sulfurized polyacrylonitrile with high C-rate and cycling performance in ether-based electrolyte for lithium sulfur batteries

Shaobo Ma
, Yang Wang
, Chuankai Fu
, Yulin Ma
, Yunzhi Gao
, Geping Yin
, Pengjian Zuo^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

24 Scopus citations

Abstract

Black phosphorus modified sulfurized polyacrylonitrile (BP-SPAN) is reported for the first time for Li-S batteries operated in ether electrolyte. The amorphous P2S5+x in BP-SPAN is crucial to suppress the shuttling effect of polysulfides and enhance the reaction kinetics. It delivers an amazing capacity of 1086 mA h g-1 (2C) and capacity retention of 91.1% (0.1C, 100th).

Original language	English
Pages (from-to)	12797-12800
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	84
DOIs	https://doi.org/10.1039/d0cc04901h
State	Published - 28 Oct 2020

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title = "Black phosphorus-modified sulfurized polyacrylonitrile with high C-rate and cycling performance in ether-based electrolyte for lithium sulfur batteries",

abstract = "Black phosphorus modified sulfurized polyacrylonitrile (BP-SPAN) is reported for the first time for Li-S batteries operated in ether electrolyte. The amorphous P2S5+x in BP-SPAN is crucial to suppress the shuttling effect of polysulfides and enhance the reaction kinetics. It delivers an amazing capacity of 1086 mA h g-1 (2C) and capacity retention of 91.1\% (0.1C, 100th).",

author = "Shaobo Ma and Yang Wang and Chuankai Fu and Yulin Ma and Yunzhi Gao and Geping Yin and Pengjian Zuo",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = oct,

day = "28",

doi = "10.1039/d0cc04901h",

language = "英语",

volume = "56",

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journal = "Chemical Communications",

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TY - JOUR

T1 - Black phosphorus-modified sulfurized polyacrylonitrile with high C-rate and cycling performance in ether-based electrolyte for lithium sulfur batteries

AU - Ma, Shaobo

AU - Wang, Yang

AU - Fu, Chuankai

AU - Ma, Yulin

AU - Gao, Yunzhi

AU - Yin, Geping

AU - Zuo, Pengjian

PY - 2020/10/28

Y1 - 2020/10/28

N2 - Black phosphorus modified sulfurized polyacrylonitrile (BP-SPAN) is reported for the first time for Li-S batteries operated in ether electrolyte. The amorphous P2S5+x in BP-SPAN is crucial to suppress the shuttling effect of polysulfides and enhance the reaction kinetics. It delivers an amazing capacity of 1086 mA h g-1 (2C) and capacity retention of 91.1% (0.1C, 100th).

AB - Black phosphorus modified sulfurized polyacrylonitrile (BP-SPAN) is reported for the first time for Li-S batteries operated in ether electrolyte. The amorphous P2S5+x in BP-SPAN is crucial to suppress the shuttling effect of polysulfides and enhance the reaction kinetics. It delivers an amazing capacity of 1086 mA h g-1 (2C) and capacity retention of 91.1% (0.1C, 100th).

UR - https://www.scopus.com/pages/publications/85094220932

U2 - 10.1039/d0cc04901h

DO - 10.1039/d0cc04901h

M3 - 文章

C2 - 32966392

AN - SCOPUS:85094220932

SN - 1359-7345

VL - 56

SP - 12797

EP - 12800

JO - Chemical Communications

JF - Chemical Communications

IS - 84

ER -

Black phosphorus-modified sulfurized polyacrylonitrile with high C-rate and cycling performance in ether-based electrolyte for lithium sulfur batteries

Abstract

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