Biphenyl Dicarboxylic-Based Ni-IRMOF-74 Film for Fast-Switching and High-Stability Electrochromism

Xueying Fan; Shen Wang; Mengyao Pan; Huan Pang; Hongbo Xu

doi:10.1021/acsenergylett.4c00492

Biphenyl Dicarboxylic-Based Ni-IRMOF-74 Film for Fast-Switching and High-Stability Electrochromism

Xueying Fan
, Shen Wang
, Mengyao Pan
, Huan Pang^*
, Hongbo Xu^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Quzhou University
University of Electronic Science and Technology of China
Yangzhou University

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Metal-organic frameworks (MOFs) are promising electrochromic materials known for their rapid response speed and ability to transition through multiple colors. However, typical MOF films suffer from slow response times and poor stability due to inappropriate pore sizes, weak substrate interaction, and limited bond reversibility. This study addresses these challenges by modifying F-doped SnO₂ with 4-mercaptobenzoic acid and fabricating Ni-IRMOF-74@MBA films using 3,3′-dihydroxy-4,4′-biphenyldicarboxylic acid. The optimized film exhibits a rapid response (1.9 s/2.0 s), high efficiency (331.0 cm² C^-1), and favorable stability (95.7% retention after 4500 cycles), transitioning from transparent to green at 0.8 V and deep-brown at 1.6 V due to Li⁺ interaction with the ligand. The resulting electrochromic device shows improved response (2.3 s/7.9 s) and stability (85% retention after 1200 cycles). This work presents a significant advancement in developing MOFs for electrochromic applications.

Original language	English
Pages (from-to)	2840-2847
Number of pages	8
Journal	ACS Energy Letters
Volume	9
Issue number	6
DOIs	https://doi.org/10.1021/acsenergylett.4c00492
State	Published - 14 Jun 2024
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Access to Document

10.1021/acsenergylett.4c00492

Cite this

@article{2ac30f4431b34d16b9ea636d1902813b,

title = "Biphenyl Dicarboxylic-Based Ni-IRMOF-74 Film for Fast-Switching and High-Stability Electrochromism",

abstract = "Metal-organic frameworks (MOFs) are promising electrochromic materials known for their rapid response speed and ability to transition through multiple colors. However, typical MOF films suffer from slow response times and poor stability due to inappropriate pore sizes, weak substrate interaction, and limited bond reversibility. This study addresses these challenges by modifying F-doped SnO2 with 4-mercaptobenzoic acid and fabricating Ni-IRMOF-74@MBA films using 3,3′-dihydroxy-4,4′-biphenyldicarboxylic acid. The optimized film exhibits a rapid response (1.9 s/2.0 s), high efficiency (331.0 cm2 C-1), and favorable stability (95.7\% retention after 4500 cycles), transitioning from transparent to green at 0.8 V and deep-brown at 1.6 V due to Li+ interaction with the ligand. The resulting electrochromic device shows improved response (2.3 s/7.9 s) and stability (85\% retention after 1200 cycles). This work presents a significant advancement in developing MOFs for electrochromic applications.",

author = "Xueying Fan and Shen Wang and Mengyao Pan and Huan Pang and Hongbo Xu",

note = "Publisher Copyright: {\textcopyright} 2024 American Chemical Society",

year = "2024",

month = jun,

day = "14",

doi = "10.1021/acsenergylett.4c00492",

language = "英语",

volume = "9",

pages = "2840--2847",

journal = "ACS Energy Letters",

issn = "2380-8195",

publisher = "American Chemical Society",

number = "6",

}

TY - JOUR

T1 - Biphenyl Dicarboxylic-Based Ni-IRMOF-74 Film for Fast-Switching and High-Stability Electrochromism

AU - Fan, Xueying

AU - Wang, Shen

AU - Pan, Mengyao

AU - Pang, Huan

AU - Xu, Hongbo

PY - 2024/6/14

Y1 - 2024/6/14

N2 - Metal-organic frameworks (MOFs) are promising electrochromic materials known for their rapid response speed and ability to transition through multiple colors. However, typical MOF films suffer from slow response times and poor stability due to inappropriate pore sizes, weak substrate interaction, and limited bond reversibility. This study addresses these challenges by modifying F-doped SnO2 with 4-mercaptobenzoic acid and fabricating Ni-IRMOF-74@MBA films using 3,3′-dihydroxy-4,4′-biphenyldicarboxylic acid. The optimized film exhibits a rapid response (1.9 s/2.0 s), high efficiency (331.0 cm2 C-1), and favorable stability (95.7% retention after 4500 cycles), transitioning from transparent to green at 0.8 V and deep-brown at 1.6 V due to Li+ interaction with the ligand. The resulting electrochromic device shows improved response (2.3 s/7.9 s) and stability (85% retention after 1200 cycles). This work presents a significant advancement in developing MOFs for electrochromic applications.

AB - Metal-organic frameworks (MOFs) are promising electrochromic materials known for their rapid response speed and ability to transition through multiple colors. However, typical MOF films suffer from slow response times and poor stability due to inappropriate pore sizes, weak substrate interaction, and limited bond reversibility. This study addresses these challenges by modifying F-doped SnO2 with 4-mercaptobenzoic acid and fabricating Ni-IRMOF-74@MBA films using 3,3′-dihydroxy-4,4′-biphenyldicarboxylic acid. The optimized film exhibits a rapid response (1.9 s/2.0 s), high efficiency (331.0 cm2 C-1), and favorable stability (95.7% retention after 4500 cycles), transitioning from transparent to green at 0.8 V and deep-brown at 1.6 V due to Li+ interaction with the ligand. The resulting electrochromic device shows improved response (2.3 s/7.9 s) and stability (85% retention after 1200 cycles). This work presents a significant advancement in developing MOFs for electrochromic applications.

UR - https://www.scopus.com/pages/publications/85194969331

U2 - 10.1021/acsenergylett.4c00492

DO - 10.1021/acsenergylett.4c00492

M3 - 文章

AN - SCOPUS:85194969331

SN - 2380-8195

VL - 9

SP - 2840

EP - 2847

JO - ACS Energy Letters

JF - ACS Energy Letters

IS - 6

ER -

Biphenyl Dicarboxylic-Based Ni-IRMOF-74 Film for Fast-Switching and High-Stability Electrochromism

Abstract

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this