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Bio-Based Shape Memory Epoxy Resin and Its Composite Derived From Gallic Acid

  • Longsha Wei
  • , Han Chen
  • , Yiwu Yan*
  • , Yudong Huang*
  • *Corresponding author for this work
  • School of Chemistry and Chemical Engineering, Harbin Institute of Technology
  • Shenzhen Academy of Aerospace Technology

Research output: Contribution to journalArticlepeer-review

Abstract

Shape memory epoxy resin (SMEP) offers high modulus and cost-effectiveness, making it suitable for aerospace components and smart building systems. This study reported a bio-based epoxy resin derived from gallic acid (bEP) with an optimized Tg of below 90°C and a flexural modulus above 2.54 GPa. The bEP demonstrated excellent shape memory properties, including a shape fixation ratio of 98% and a shape recovery ratio of 97%. Additionally, the composites prepared by the bEP showed excellent shape memory performance, achieving a 96% fixation ratio and a 95% recovery ratio, and can quickly recover 95% of their deformation within 30 s.

Original languageEnglish
Article numbere57802
JournalJournal of Applied Polymer Science
Volume142
Issue number46
DOIs
StatePublished - 10 Dec 2025
Externally publishedYes

Keywords

  • biomaterials
  • composites
  • glass transition
  • resins
  • thermosets

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