Binuclear cluster-to-cluster-based supramolecular compounds: Design, assembly, and enhanced third-order nonlinear optical performances of {[Et 4N]2[MoOS3Cu2(μ-CN)] 2·2aniline}n and {[Et4N] 4[MoOS3Cu3CN(μ′-CN)] 2(μ-CN)2}n

Wen Hua Zhang; Ying Lin Song; Yong Zhang; Jian Ping Lang

doi:10.1021/cg070235n

Binuclear cluster-to-cluster-based supramolecular compounds: Design, assembly, and enhanced third-order nonlinear optical performances of {[Et ₄N]₂[MoOS₃Cu₂(μ-CN)] ₂·2aniline}_n and {[Et₄N] ₄[MoOS₃Cu₃CN(μ′-CN)] ₂(μ-CN)₂}_n

Wen Hua Zhang
, Ying Lin Song
, Yong Zhang
, Jian Ping Lang^*

^*Corresponding author for this work

Soochow University
Nanjing University

Research output: Contribution to journal › Article › peer-review

90 Scopus citations

Abstract

Reaction of a cluster precursor [Et₄N]₂[MoOS ₃(CuCN)] (1) with equimolar [Cu(MeCN)₄](PF₆) in MeCN/aniline gave rise to an interesting polymeric cluster {[Et ₄N]₂[MoOS₃Cu₂(μ-CN)I ₂·;aniline}_n (2), while treatment of 1 in MeCN with 2 equiv of CuCN and KCN in H₂O afforded the other polymeric cluster {[Et₄N]₄[MoOS₃Cu₃CN(μ′-CN)] ₂(μ-CN)₂}_n (3). Generated by addition of one or two Cu⁺ onto the [MoOS₃Cu] cluster core in 1, the butterfly shaped [MoOS₃Cu₂] fragment in 2 or the incomplete cubanelike [MoOS₃Cu₃] fragment in 3 was dimerized into a prismatic [MoOS₃Cu₂]₂ cage core or a double incomplete cubanelike [MoOS₃Cu₃] ₂ core. These two expanded cores serve as a unique planar 4-connecting node (2) or a rare chairlike 4-connecting node (3) to link equivalent nodes via cyanide bridges, forming two kinds of different 2D (4,4) networks. The third-order nonlinear optical (NLO) properties of 1-3 in DMF were also investigated.

Original language	English
Pages (from-to)	253-258
Number of pages	6
Journal	Crystal Growth and Design
Volume	8
Issue number	1
DOIs	https://doi.org/10.1021/cg070235n
State	Published - Jan 2008
Externally published	Yes

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@article{0d5e58d3d0914f5dbb0537d01bd5532e,

title = "Binuclear cluster-to-cluster-based supramolecular compounds: Design, assembly, and enhanced third-order nonlinear optical performances of \{[Et 4N]2[MoOS3Cu2(μ-CN)] 2·2aniline\}n and \{[Et4N] 4[MoOS3Cu3CN(μ′-CN)] 2(μ-CN)2\}n",

abstract = "Reaction of a cluster precursor [Et4N]2[MoOS 3(CuCN)] (1) with equimolar [Cu(MeCN)4](PF6) in MeCN/aniline gave rise to an interesting polymeric cluster \{[Et 4N]2[MoOS3Cu2(μ-CN)I 2·;aniline\}n (2), while treatment of 1 in MeCN with 2 equiv of CuCN and KCN in H2O afforded the other polymeric cluster \{[Et4N]4[MoOS3Cu3CN(μ′-CN)] 2(μ-CN)2\}n (3). Generated by addition of one or two Cu+ onto the [MoOS3Cu] cluster core in 1, the butterfly shaped [MoOS3Cu2] fragment in 2 or the incomplete cubanelike [MoOS3Cu3] fragment in 3 was dimerized into a prismatic [MoOS3Cu2]2 cage core or a double incomplete cubanelike [MoOS3Cu3] 2 core. These two expanded cores serve as a unique planar 4-connecting node (2) or a rare chairlike 4-connecting node (3) to link equivalent nodes via cyanide bridges, forming two kinds of different 2D (4,4) networks. The third-order nonlinear optical (NLO) properties of 1-3 in DMF were also investigated.",

author = "Zhang, \{Wen Hua\} and Song, \{Ying Lin\} and Yong Zhang and Lang, \{Jian Ping\}",

year = "2008",

month = jan,

doi = "10.1021/cg070235n",

language = "英语",

volume = "8",

pages = "253--258",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "1",

}

Binuclear cluster-to-cluster-based supramolecular compounds: Design, assembly, and enhanced third-order nonlinear optical performances of {[Et ₄N]₂[MoOS₃Cu₂(μ-CN)] ₂·2aniline}_n and {[Et₄N] ₄[MoOS₃Cu₃CN(μ′-CN)] ₂(μ-CN)₂}_n. / Zhang, Wen Hua; Song, Ying Lin; Zhang, Yong et al.
In: Crystal Growth and Design, Vol. 8, No. 1, 01.2008, p. 253-258.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Binuclear cluster-to-cluster-based supramolecular compounds

T2 - Design, assembly, and enhanced third-order nonlinear optical performances of {[Et 4N]2[MoOS3Cu2(μ-CN)] 2·2aniline}n and {[Et4N] 4[MoOS3Cu3CN(μ′-CN)] 2(μ-CN)2}n

AU - Zhang, Wen Hua

AU - Song, Ying Lin

AU - Zhang, Yong

AU - Lang, Jian Ping

PY - 2008/1

Y1 - 2008/1

N2 - Reaction of a cluster precursor [Et4N]2[MoOS 3(CuCN)] (1) with equimolar [Cu(MeCN)4](PF6) in MeCN/aniline gave rise to an interesting polymeric cluster {[Et 4N]2[MoOS3Cu2(μ-CN)I 2·;aniline}n (2), while treatment of 1 in MeCN with 2 equiv of CuCN and KCN in H2O afforded the other polymeric cluster {[Et4N]4[MoOS3Cu3CN(μ′-CN)] 2(μ-CN)2}n (3). Generated by addition of one or two Cu+ onto the [MoOS3Cu] cluster core in 1, the butterfly shaped [MoOS3Cu2] fragment in 2 or the incomplete cubanelike [MoOS3Cu3] fragment in 3 was dimerized into a prismatic [MoOS3Cu2]2 cage core or a double incomplete cubanelike [MoOS3Cu3] 2 core. These two expanded cores serve as a unique planar 4-connecting node (2) or a rare chairlike 4-connecting node (3) to link equivalent nodes via cyanide bridges, forming two kinds of different 2D (4,4) networks. The third-order nonlinear optical (NLO) properties of 1-3 in DMF were also investigated.

AB - Reaction of a cluster precursor [Et4N]2[MoOS 3(CuCN)] (1) with equimolar [Cu(MeCN)4](PF6) in MeCN/aniline gave rise to an interesting polymeric cluster {[Et 4N]2[MoOS3Cu2(μ-CN)I 2·;aniline}n (2), while treatment of 1 in MeCN with 2 equiv of CuCN and KCN in H2O afforded the other polymeric cluster {[Et4N]4[MoOS3Cu3CN(μ′-CN)] 2(μ-CN)2}n (3). Generated by addition of one or two Cu+ onto the [MoOS3Cu] cluster core in 1, the butterfly shaped [MoOS3Cu2] fragment in 2 or the incomplete cubanelike [MoOS3Cu3] fragment in 3 was dimerized into a prismatic [MoOS3Cu2]2 cage core or a double incomplete cubanelike [MoOS3Cu3] 2 core. These two expanded cores serve as a unique planar 4-connecting node (2) or a rare chairlike 4-connecting node (3) to link equivalent nodes via cyanide bridges, forming two kinds of different 2D (4,4) networks. The third-order nonlinear optical (NLO) properties of 1-3 in DMF were also investigated.

UR - https://www.scopus.com/pages/publications/38449118101

U2 - 10.1021/cg070235n

DO - 10.1021/cg070235n

M3 - 文章

AN - SCOPUS:38449118101

SN - 1528-7483

VL - 8

SP - 253

EP - 258

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 1