Bi(Ⅲ) and Ce(Ⅳ) functionalized carbon nitride photocatalyst for antibiotic degradation: Synthesis, toxicity, and mechanism investigations

Graphite-phase carbon nitride (g-C₃N₄) has shown great potential for antibiotic wastewater treatment due to its unique electronic structure and corresponding to visible light. In this study, a series of Bi/Ce/g-C₃N₄ photocatalysts with different doping amount were developed by direct calcination method for Rhodamine B and sulfamethoxazole photocatalytic degradation. The experiment result shows that the photocatalytic performance of Bi/Ce/g-C₃N₄ catalysts were better than that of single component samples. Under the optimal experimental conditions, the degradation rates of RhB (20 min) and SMX (120 min) by 3Bi/Ce/g-C₃N₄ reached 98.3% and 70.5%, respectively. The theoretical calculation results of DFT show that after Bi and Ce doping modification, the band-gap width of g-C₃N₄ is reduced to 1.215 eV and carrier migration rate is greatly improved. The enhanced photocatalytic activity was mainly attributed to the capture of electrons after doping modification, which inhibition of photogenerated carriers recombination and reduced the gap width. The cyclic treatment experiment of sulfamethoxazole showed that Bi/Ce/g-C₃N₄ catalysts had good stability. Ecosar evaluation and leaching toxicity test showed that Bi/Ce/g-C₃N₄ can be safely used for wastewater treatment. This study provides a perfect strategy for modifying g-C₃N₄ and a new way to improve the photocatalytic performance.