Benzoselenophenylpyridine platinum complexes: Green: versus red phosphorescence towards hybrid OLEDs

Alla Petrenko; Karolis Leitonas; Dmytro Volyniuk; Gleb V. Baryshnikov; Sergey Belyakov; Boris F. Minaev; Hans Ågren; Hranush Durgaryan; Juozas Vidas Gražulevičius; Pavel Arsenyan

doi:10.1039/d0dt00214c

Benzoselenophenylpyridine platinum complexes: Green: versus red phosphorescence towards hybrid OLEDs

Alla Petrenko
, Karolis Leitonas
, Dmytro Volyniuk
, Gleb V. Baryshnikov
, Sergey Belyakov
, Boris F. Minaev
, Hans Ågren
, Hranush Durgaryan
, Juozas Vidas Gražulevičius
, Pavel Arsenyan

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

The first examples of phosphorescent platinum complexes bearing 2-and 3-(2-pyridyl)benzo[b]selenophenes (PyBSe) were synthesized and fully characterized. Almost identical ionization potential values (5.6 and 5.58 eV) of the solid samples of the Pt complexes were obtained by electron photoemission spectroscopy. Having slightly different molecular design, the solid solutions of the complexes emitted efficient green and red phosphorescence with absolute quantum yields of 52% (for green) and 11.6% (for red). It is demonstrated that the platinum complexes synthesized can be used as phosphorescent dopants for hybrid solution-processable OLEDs.

Original language	English
Pages (from-to)	3393-3397
Number of pages	5
Journal	Dalton Transactions
Volume	49
Issue number	11
DOIs	https://doi.org/10.1039/d0dt00214c
State	Published - 21 Mar 2020
Externally published	Yes

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title = "Benzoselenophenylpyridine platinum complexes: Green: versus red phosphorescence towards hybrid OLEDs",

abstract = "The first examples of phosphorescent platinum complexes bearing 2-and 3-(2-pyridyl)benzo[b]selenophenes (PyBSe) were synthesized and fully characterized. Almost identical ionization potential values (5.6 and 5.58 eV) of the solid samples of the Pt complexes were obtained by electron photoemission spectroscopy. Having slightly different molecular design, the solid solutions of the complexes emitted efficient green and red phosphorescence with absolute quantum yields of 52\% (for green) and 11.6\% (for red). It is demonstrated that the platinum complexes synthesized can be used as phosphorescent dopants for hybrid solution-processable OLEDs.",

author = "Alla Petrenko and Karolis Leitonas and Dmytro Volyniuk and Baryshnikov, \{Gleb V.\} and Sergey Belyakov and Minaev, \{Boris F.\} and Hans {\AA}gren and Hranush Durgaryan and Gra{\v z}ulevi{\v c}ius, \{Juozas Vidas\} and Pavel Arsenyan",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = mar,

day = "21",

doi = "10.1039/d0dt00214c",

language = "英语",

volume = "49",

pages = "3393--3397",

journal = "Dalton Transactions",

issn = "1477-9226",

publisher = "Royal Society of Chemistry",

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}

TY - JOUR

T1 - Benzoselenophenylpyridine platinum complexes

T2 - Green: versus red phosphorescence towards hybrid OLEDs

AU - Petrenko, Alla

AU - Leitonas, Karolis

AU - Volyniuk, Dmytro

AU - Baryshnikov, Gleb V.

AU - Belyakov, Sergey

AU - Minaev, Boris F.

AU - Ågren, Hans

AU - Durgaryan, Hranush

AU - Gražulevičius, Juozas Vidas

AU - Arsenyan, Pavel

PY - 2020/3/21

Y1 - 2020/3/21

N2 - The first examples of phosphorescent platinum complexes bearing 2-and 3-(2-pyridyl)benzo[b]selenophenes (PyBSe) were synthesized and fully characterized. Almost identical ionization potential values (5.6 and 5.58 eV) of the solid samples of the Pt complexes were obtained by electron photoemission spectroscopy. Having slightly different molecular design, the solid solutions of the complexes emitted efficient green and red phosphorescence with absolute quantum yields of 52% (for green) and 11.6% (for red). It is demonstrated that the platinum complexes synthesized can be used as phosphorescent dopants for hybrid solution-processable OLEDs.

AB - The first examples of phosphorescent platinum complexes bearing 2-and 3-(2-pyridyl)benzo[b]selenophenes (PyBSe) were synthesized and fully characterized. Almost identical ionization potential values (5.6 and 5.58 eV) of the solid samples of the Pt complexes were obtained by electron photoemission spectroscopy. Having slightly different molecular design, the solid solutions of the complexes emitted efficient green and red phosphorescence with absolute quantum yields of 52% (for green) and 11.6% (for red). It is demonstrated that the platinum complexes synthesized can be used as phosphorescent dopants for hybrid solution-processable OLEDs.

UR - https://www.scopus.com/pages/publications/85082096459

U2 - 10.1039/d0dt00214c

DO - 10.1039/d0dt00214c

M3 - 文章

C2 - 32129412

AN - SCOPUS:85082096459

SN - 1477-9226

VL - 49

SP - 3393

EP - 3397

JO - Dalton Transactions

JF - Dalton Transactions

IS - 11

ER -

Benzoselenophenylpyridine platinum complexes: Green: versus red phosphorescence towards hybrid OLEDs

Abstract

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