B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane

Fangwei Ding; Yiliang Zhang; Rong Zhao; Yanqiu Jiang; Robert Li Yuan Bao; Kaifeng Lin; Lei Shi

doi:10.1039/c7cc04709f

B(C₆F₅)₃-Promoted hydrogenations of N-heterocycles with ammonia borane

Fangwei Ding
, Yiliang Zhang
, Rong Zhao
, Yanqiu Jiang
, Robert Li Yuan Bao
, Kaifeng Lin
, Lei Shi^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Harbin Institute of Technology Shenzhen

Research output: Contribution to journal › Article › peer-review

66 Scopus citations

Abstract

A transition-metal-free method for the B(C₆F₅)₃-promoted hydrogenations of N-heterocycles using ammonia borane under mild reaction conditions has been developed. The reaction affords a broad range of hydrogenated products in moderate to good yields. The enantioselective versions for the corresponding products were also investigated via our approach, showing good feasibility.

Original language	English
Pages (from-to)	9262-9264
Number of pages	3
Journal	Chemical Communications
Volume	53
Issue number	66
DOIs	https://doi.org/10.1039/c7cc04709f
State	Published - 2017
Externally published	Yes

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10.1039/c7cc04709f

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title = "B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane",

abstract = "A transition-metal-free method for the B(C6F5)3-promoted hydrogenations of N-heterocycles using ammonia borane under mild reaction conditions has been developed. The reaction affords a broad range of hydrogenated products in moderate to good yields. The enantioselective versions for the corresponding products were also investigated via our approach, showing good feasibility.",

author = "Fangwei Ding and Yiliang Zhang and Rong Zhao and Yanqiu Jiang and Bao, \{Robert Li Yuan\} and Kaifeng Lin and Lei Shi",

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T1 - B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane

AU - Ding, Fangwei

AU - Zhang, Yiliang

AU - Zhao, Rong

AU - Jiang, Yanqiu

AU - Bao, Robert Li Yuan

AU - Lin, Kaifeng

AU - Shi, Lei

PY - 2017

Y1 - 2017

N2 - A transition-metal-free method for the B(C6F5)3-promoted hydrogenations of N-heterocycles using ammonia borane under mild reaction conditions has been developed. The reaction affords a broad range of hydrogenated products in moderate to good yields. The enantioselective versions for the corresponding products were also investigated via our approach, showing good feasibility.

AB - A transition-metal-free method for the B(C6F5)3-promoted hydrogenations of N-heterocycles using ammonia borane under mild reaction conditions has been developed. The reaction affords a broad range of hydrogenated products in moderate to good yields. The enantioselective versions for the corresponding products were also investigated via our approach, showing good feasibility.

UR - https://www.scopus.com/pages/publications/85027400693

U2 - 10.1039/c7cc04709f

DO - 10.1039/c7cc04709f

M3 - 文章

C2 - 28771256

AN - SCOPUS:85027400693

SN - 1359-7345

VL - 53

SP - 9262

EP - 9264

JO - Chemical Communications

JF - Chemical Communications

IS - 66

ER -

B(C₆F₅)₃-Promoted hydrogenations of N-heterocycles with ammonia borane

Abstract

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