B(C6F5)3-Catalyzed Deoxygenation of Sulfoxides and Amine N-Oxides with Hydrosilanes

Fangwei Ding; Yanqiu Jiang; Shaoyan Gan; Robert Li Yuan Bao; Kaifeng Lin; Lei Shi

doi:10.1002/ejoc.201700489

B(C₆F₅)₃-Catalyzed Deoxygenation of Sulfoxides and Amine N-Oxides with Hydrosilanes

Fangwei Ding
, Yanqiu Jiang
, Shaoyan Gan
, Robert Li Yuan Bao
, Kaifeng Lin
, Lei Shi^*

^*Corresponding author for this work

School of Chemistry and Chemical Engineering, Harbin Institute of Technology
Harbin Institute of Technology Shenzhen
Jingchu University of Technology

Research output: Contribution to journal › Article › peer-review

29 Scopus citations

Abstract

An efficient strategy for the deoxygenation of sulfoxides and amine N-oxides by using B(C₆F₅)₃ and hydrosilanes was developed. This method provided the corresponding aromatic and aliphatic products in good to high yields and showed good functional-group tolerance under mild conditions.

Original language	English
Pages (from-to)	3427-3430
Number of pages	4
Journal	European Journal of Organic Chemistry
Volume	2017
Issue number	24
DOIs	https://doi.org/10.1002/ejoc.201700489
State	Published - 30 Jun 2017
Externally published	Yes

Keywords

Amines
Deoxygenation
Hydrosilanes
Lewis acids
Sulfur

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10.1002/ejoc.201700489

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@article{f52ec52da75049aebc5c33d529207ef3,

title = "B(C6F5)3-Catalyzed Deoxygenation of Sulfoxides and Amine N-Oxides with Hydrosilanes",

abstract = "An efficient strategy for the deoxygenation of sulfoxides and amine N-oxides by using B(C6F5)3 and hydrosilanes was developed. This method provided the corresponding aromatic and aliphatic products in good to high yields and showed good functional-group tolerance under mild conditions.",

keywords = "Amines, Deoxygenation, Hydrosilanes, Lewis acids, Sulfur",

author = "Fangwei Ding and Yanqiu Jiang and Shaoyan Gan and Bao, \{Robert Li Yuan\} and Kaifeng Lin and Lei Shi",

note = "Publisher Copyright: {\textcopyright} 2017 WILEY-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = jun,

day = "30",

doi = "10.1002/ejoc.201700489",

language = "英语",

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journal = "European Journal of Organic Chemistry",

issn = "1434-193X",

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TY - JOUR

T1 - B(C6F5)3-Catalyzed Deoxygenation of Sulfoxides and Amine N-Oxides with Hydrosilanes

AU - Ding, Fangwei

AU - Jiang, Yanqiu

AU - Gan, Shaoyan

AU - Bao, Robert Li Yuan

AU - Lin, Kaifeng

AU - Shi, Lei

PY - 2017/6/30

Y1 - 2017/6/30

N2 - An efficient strategy for the deoxygenation of sulfoxides and amine N-oxides by using B(C6F5)3 and hydrosilanes was developed. This method provided the corresponding aromatic and aliphatic products in good to high yields and showed good functional-group tolerance under mild conditions.

AB - An efficient strategy for the deoxygenation of sulfoxides and amine N-oxides by using B(C6F5)3 and hydrosilanes was developed. This method provided the corresponding aromatic and aliphatic products in good to high yields and showed good functional-group tolerance under mild conditions.

KW - Amines

KW - Deoxygenation

KW - Hydrosilanes

KW - Lewis acids

KW - Sulfur

UR - https://www.scopus.com/pages/publications/85021438934

U2 - 10.1002/ejoc.201700489

DO - 10.1002/ejoc.201700489

M3 - 文章

AN - SCOPUS:85021438934

SN - 1434-193X

VL - 2017

SP - 3427

EP - 3430

JO - European Journal of Organic Chemistry

JF - European Journal of Organic Chemistry

IS - 24

ER -

B(C₆F₅)₃-Catalyzed Deoxygenation of Sulfoxides and Amine N-Oxides with Hydrosilanes

Abstract

Keywords

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