Base-Promoted Direct Synthesis of Sulfinates from N -Sulfonyl­hydrazones under Metal-Free Conditions

Yuan Zhao Ji; Qin Xi Wu; Hui Jing Li; Dong Hui Luo; Yan Chao Wu

doi:10.1055/s-0039-1690754

Base-Promoted Direct Synthesis of Sulfinates from N -Sulfonylhydrazones under Metal-Free Conditions

Yuan Zhao Ji
, Qin Xi Wu
, Hui Jing Li^*
, Dong Hui Luo
, Yan Chao Wu

^*Corresponding author for this work

School of Marine Science and Technology, Harbin Institute of Technology Weihai
Weihai Institute of Marine Biomedical Industrial Technology

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

A base-promoted direct synthesis of sulfinates from N -sulfonylhydrazones is described. Various N -sulfonylhydrazones, derived from aldehydes and ketones, are converted into the corresponding sulfinates in moderate to good yields. This protocol possesses many advantages such as readily available and stable starting materials, broad substrate scope, and metal-free reaction conditions.

Original language	English
Pages (from-to)	755-762
Number of pages	8
Journal	Synthesis (Germany)
Volume	52
Issue number	5
DOIs	https://doi.org/10.1055/s-0039-1690754
State	Published - 12 Feb 2020
Externally published	Yes

Keywords

DIPEA
Sulfinates
carbonyl compounds
hydrazones
sulfonylhydrazines

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10.1055/s-0039-1690754

Cite this

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title = "Base-Promoted Direct Synthesis of Sulfinates from N -Sulfonylhydrazones under Metal-Free Conditions",

abstract = "A base-promoted direct synthesis of sulfinates from N -sulfonylhydrazones is described. Various N -sulfonylhydrazones, derived from aldehydes and ketones, are converted into the corresponding sulfinates in moderate to good yields. This protocol possesses many advantages such as readily available and stable starting materials, broad substrate scope, and metal-free reaction conditions.",

keywords = "DIPEA, Sulfinates, carbonyl compounds, hydrazones, sulfonylhydrazines",

author = "Ji, \{Yuan Zhao\} and Wu, \{Qin Xi\} and Li, \{Hui Jing\} and Luo, \{Dong Hui\} and Wu, \{Yan Chao\}",

year = "2020",

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day = "12",

doi = "10.1055/s-0039-1690754",

language = "英语",

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T1 - Base-Promoted Direct Synthesis of Sulfinates from N -Sulfonylhydrazones under Metal-Free Conditions

AU - Ji, Yuan Zhao

AU - Wu, Qin Xi

AU - Li, Hui Jing

AU - Luo, Dong Hui

AU - Wu, Yan Chao

PY - 2020/2/12

Y1 - 2020/2/12

N2 - A base-promoted direct synthesis of sulfinates from N -sulfonylhydrazones is described. Various N -sulfonylhydrazones, derived from aldehydes and ketones, are converted into the corresponding sulfinates in moderate to good yields. This protocol possesses many advantages such as readily available and stable starting materials, broad substrate scope, and metal-free reaction conditions.

AB - A base-promoted direct synthesis of sulfinates from N -sulfonylhydrazones is described. Various N -sulfonylhydrazones, derived from aldehydes and ketones, are converted into the corresponding sulfinates in moderate to good yields. This protocol possesses many advantages such as readily available and stable starting materials, broad substrate scope, and metal-free reaction conditions.

KW - DIPEA

KW - Sulfinates

KW - carbonyl compounds

KW - hydrazones

KW - sulfonylhydrazines

UR - https://www.scopus.com/pages/publications/85079657737

U2 - 10.1055/s-0039-1690754

DO - 10.1055/s-0039-1690754

M3 - 文章

AN - SCOPUS:85079657737

SN - 0039-7881

VL - 52

SP - 755

EP - 762

JO - Synthesis (Germany)

JF - Synthesis (Germany)

IS - 5

ER -

Base-Promoted Direct Synthesis of Sulfinates from N -Sulfonylhydrazones under Metal-Free Conditions

Abstract

Keywords

Access to Document

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Cite this

Base-Promoted Direct Synthesis of Sulfinates from N -Sulfonyl­hydrazones under Metal-Free Conditions

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this

Base-Promoted Direct Synthesis of Sulfinates from N -Sulfonylhydrazones under Metal-Free Conditions