Auxiliary ligand-assisted two novel one-dimensional indium coordination polymers: Synthesis, crystal structures and photoluminescence characterization effected by solvent and temperature

Xin Ming Wang; Rui Qing Fan; Ping Wang; Liang Sheng Qiang; Yu Lin Yang; Yu Lei Wang

doi:10.1016/j.inoche.2014.11.002

Auxiliary ligand-assisted two novel one-dimensional indium coordination polymers: Synthesis, crystal structures and photoluminescence characterization effected by solvent and temperature

Xin Ming Wang
, Rui Qing Fan^*
, Ping Wang
, Liang Sheng Qiang
, Yu Lin Yang
, Yu Lei Wang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Review article › peer-review

6 Scopus citations

Abstract

Two new indium coordination polymers (CPs) with mixed-ligand formulated as {[In(1,4-bda)_1.5(phen)]•2H₂O}_n (In1) and {In(1,4-bda)(2,2′-bipy)Cl}_n (In2) (1,4-H₂bda = 1,4-benzenedicarboxylic acid; phen = 1,10-phenanthrolin; 2,2′-bipy= 2,2′-bipyridine) have been synthesized and characterized by single-crystal X-ray diffraction, infrared (IR), elemental analysis and thermal gravimetric analyses (TGA). In1 exhibits one-dimensional (1D) ladder chain, which further forms three-dimensional (3D) structure with π⋯π stacking interaction. Formation of 3D compact supramolecular framework in In2 is generated through C-H...Cl hydrogen bonding contacts and π⋯π stacking interaction. The photoluminescence (PL) characterizations to In1 and In2 affected by solvent and temperature are studied in detail. Thermogravimetric curves showed that In1 and In2 start to undergo phase transition until ca. 450°C and 495°C, respectively.

Original language	English
Pages (from-to)	29-35
Number of pages	7
Journal	Inorganic Chemistry Communications
Volume	51
DOIs	https://doi.org/10.1016/j.inoche.2014.11.002
State	Published - Jan 2015

Keywords

Indium coordination polymers
Photoluminescence
Supramolecular framework
Thermogravimetric curves

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10.1016/j.inoche.2014.11.002

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@article{d87344864c80428e8b30e734fbbb297d,

title = "Auxiliary ligand-assisted two novel one-dimensional indium coordination polymers: Synthesis, crystal structures and photoluminescence characterization effected by solvent and temperature",

abstract = "Two new indium coordination polymers (CPs) with mixed-ligand formulated as \{[In(1,4-bda)1.5(phen)]•2H2O\}n (In1) and \{In(1,4-bda)(2,2′-bipy)Cl\}n (In2) (1,4-H2bda = 1,4-benzenedicarboxylic acid; phen = 1,10-phenanthrolin; 2,2′-bipy= 2,2′-bipyridine) have been synthesized and characterized by single-crystal X-ray diffraction, infrared (IR), elemental analysis and thermal gravimetric analyses (TGA). In1 exhibits one-dimensional (1D) ladder chain, which further forms three-dimensional (3D) structure with π⋯π stacking interaction. Formation of 3D compact supramolecular framework in In2 is generated through C-H...Cl hydrogen bonding contacts and π⋯π stacking interaction. The photoluminescence (PL) characterizations to In1 and In2 affected by solvent and temperature are studied in detail. Thermogravimetric curves showed that In1 and In2 start to undergo phase transition until ca. 450°C and 495°C, respectively.",

keywords = "Indium coordination polymers, Photoluminescence, Supramolecular framework, Thermogravimetric curves",

author = "Wang, \{Xin Ming\} and Fan, \{Rui Qing\} and Ping Wang and Qiang, \{Liang Sheng\} and Yang, \{Yu Lin\} and Wang, \{Yu Lei\}",

year = "2015",

month = jan,

doi = "10.1016/j.inoche.2014.11.002",

language = "英语",

volume = "51",

pages = "29--35",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

Auxiliary ligand-assisted two novel one-dimensional indium coordination polymers: Synthesis, crystal structures and photoluminescence characterization effected by solvent and temperature. / Wang, Xin Ming; Fan, Rui Qing; Wang, Ping et al.
In: Inorganic Chemistry Communications, Vol. 51, 01.2015, p. 29-35.

Research output: Contribution to journal › Review article › peer-review

TY - JOUR

T1 - Auxiliary ligand-assisted two novel one-dimensional indium coordination polymers

T2 - Synthesis, crystal structures and photoluminescence characterization effected by solvent and temperature

AU - Wang, Xin Ming

AU - Fan, Rui Qing

AU - Wang, Ping

AU - Qiang, Liang Sheng

AU - Yang, Yu Lin

AU - Wang, Yu Lei

PY - 2015/1

Y1 - 2015/1

N2 - Two new indium coordination polymers (CPs) with mixed-ligand formulated as {[In(1,4-bda)1.5(phen)]•2H2O}n (In1) and {In(1,4-bda)(2,2′-bipy)Cl}n (In2) (1,4-H2bda = 1,4-benzenedicarboxylic acid; phen = 1,10-phenanthrolin; 2,2′-bipy= 2,2′-bipyridine) have been synthesized and characterized by single-crystal X-ray diffraction, infrared (IR), elemental analysis and thermal gravimetric analyses (TGA). In1 exhibits one-dimensional (1D) ladder chain, which further forms three-dimensional (3D) structure with π⋯π stacking interaction. Formation of 3D compact supramolecular framework in In2 is generated through C-H...Cl hydrogen bonding contacts and π⋯π stacking interaction. The photoluminescence (PL) characterizations to In1 and In2 affected by solvent and temperature are studied in detail. Thermogravimetric curves showed that In1 and In2 start to undergo phase transition until ca. 450°C and 495°C, respectively.

AB - Two new indium coordination polymers (CPs) with mixed-ligand formulated as {[In(1,4-bda)1.5(phen)]•2H2O}n (In1) and {In(1,4-bda)(2,2′-bipy)Cl}n (In2) (1,4-H2bda = 1,4-benzenedicarboxylic acid; phen = 1,10-phenanthrolin; 2,2′-bipy= 2,2′-bipyridine) have been synthesized and characterized by single-crystal X-ray diffraction, infrared (IR), elemental analysis and thermal gravimetric analyses (TGA). In1 exhibits one-dimensional (1D) ladder chain, which further forms three-dimensional (3D) structure with π⋯π stacking interaction. Formation of 3D compact supramolecular framework in In2 is generated through C-H...Cl hydrogen bonding contacts and π⋯π stacking interaction. The photoluminescence (PL) characterizations to In1 and In2 affected by solvent and temperature are studied in detail. Thermogravimetric curves showed that In1 and In2 start to undergo phase transition until ca. 450°C and 495°C, respectively.

KW - Indium coordination polymers

KW - Photoluminescence

KW - Supramolecular framework

KW - Thermogravimetric curves

UR - https://www.scopus.com/pages/publications/84910643959

U2 - 10.1016/j.inoche.2014.11.002

DO - 10.1016/j.inoche.2014.11.002

M3 - 文献综述

AN - SCOPUS:84910643959

SN - 1387-7003

VL - 51

SP - 29

EP - 35

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Auxiliary ligand-assisted two novel one-dimensional indium coordination polymers: Synthesis, crystal structures and photoluminescence characterization effected by solvent and temperature

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Keywords

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