Abstract
Surface modification of β-FeSi2 by ZnO is verified to be an effective way to prevent oxidation and enhance thermoelectric (TE) properties of β-FeSi2. A simple approach is developed to fabricate well-covered, high-density and stable ZnO nanoparticles-coated β-FeSi 2 (ZnOβ-FeSi2). First, β-FeSi2 (n-type Fe0.98Co0.02Si2) particles were prepared by mechanical alloying (MA) and pre-treated in sodium oleate solution to increase the polarity of the surface. Then, the pre-treated β-FeSi 2 particles were successfully coated by ZnO nanoparticles during sol-gel process. Compared with that of uncoated β-FeSi2, antioxidation and thermoelectric performance of ZnOβ-FeSi2 materials is improved distinctly.
| Original language | English |
|---|---|
| Pages (from-to) | 331-336 |
| Number of pages | 6 |
| Journal | Materials Chemistry and Physics |
| Volume | 129 |
| Issue number | 1-2 |
| DOIs | |
| State | Published - 15 Sep 2011 |
Keywords
- Oxidation
- Thermoelectric effects
- ZnO nanoparticles-coating
- β-FeSi semiconductors
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