An X-ray absorption, photoemission, and raman study of the interaction between SnO2 nanoparticle and carbon nanotube

J. G. Zhou; H. T. Fang; J. M. Maley; J. Y.P. Ko; M. Murphy; Y. Chu; R. Sammynaiken; T. K. Sham

doi:10.1021/jp810639y

An X-ray absorption, photoemission, and raman study of the interaction between SnO₂ nanoparticle and carbon nanotube

J. G. Zhou
, H. T. Fang
, J. M. Maley
, J. Y.P. Ko
, M. Murphy
, Y. Chu
, R. Sammynaiken
, T. K. Sham

Western University
University of Saskatchewan
Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

81 Scopus citations

Abstract

The interaction between SnO₂ and substrate in SnO₂ nanoparieles (NPs) - carbon nanotubes (CNTs) composite has been studied by X-ray absorption near-edge structures (XANES) at Sn M_5,4, O K-edge and C K-edge. SnO₂ NPs in the composite have a rutile crystal structure with abundant surface states. The variation in resonance features of the XANES strongly supports that the crystalline SnO₂ NPs interact with CNTs through synergic bonding involving charge redistribution between C 2p-derived states and the valence and conduction bands in SnO₂ NPs via interaction at the interface facilitated by oxidation treatment of the CNT prior to composite formation. Raman and ultraviolet photoelectron spectroscopy (UPS) results support the synergic bonding interaction. Such interaction is expected not only to immobilize SnO₂ NPs on CNT but also to improve the conductivity of SnO₂ NPs.

Original language	English
Pages (from-to)	6114-6117
Number of pages	4
Journal	Journal of Physical Chemistry C
Volume	113
Issue number	15
DOIs	https://doi.org/10.1021/jp810639y
State	Published - 16 Apr 2009
Externally published	Yes

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10.1021/jp810639y

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title = "An X-ray absorption, photoemission, and raman study of the interaction between SnO2 nanoparticle and carbon nanotube",

abstract = "The interaction between SnO2 and substrate in SnO2 nanoparieles (NPs) - carbon nanotubes (CNTs) composite has been studied by X-ray absorption near-edge structures (XANES) at Sn M5,4, O K-edge and C K-edge. SnO2 NPs in the composite have a rutile crystal structure with abundant surface states. The variation in resonance features of the XANES strongly supports that the crystalline SnO2 NPs interact with CNTs through synergic bonding involving charge redistribution between C 2p-derived states and the valence and conduction bands in SnO2 NPs via interaction at the interface facilitated by oxidation treatment of the CNT prior to composite formation. Raman and ultraviolet photoelectron spectroscopy (UPS) results support the synergic bonding interaction. Such interaction is expected not only to immobilize SnO2 NPs on CNT but also to improve the conductivity of SnO2 NPs.",

author = "Zhou, \{J. G.\} and Fang, \{H. T.\} and Maley, \{J. M.\} and Ko, \{J. Y.P.\} and M. Murphy and Y. Chu and R. Sammynaiken and Sham, \{T. K.\}",

year = "2009",

month = apr,

day = "16",

doi = "10.1021/jp810639y",

language = "英语",

volume = "113",

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journal = "Journal of Physical Chemistry C",

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TY - JOUR

T1 - An X-ray absorption, photoemission, and raman study of the interaction between SnO2 nanoparticle and carbon nanotube

AU - Zhou, J. G.

AU - Fang, H. T.

AU - Maley, J. M.

AU - Ko, J. Y.P.

AU - Murphy, M.

AU - Chu, Y.

AU - Sammynaiken, R.

AU - Sham, T. K.

PY - 2009/4/16

Y1 - 2009/4/16

N2 - The interaction between SnO2 and substrate in SnO2 nanoparieles (NPs) - carbon nanotubes (CNTs) composite has been studied by X-ray absorption near-edge structures (XANES) at Sn M5,4, O K-edge and C K-edge. SnO2 NPs in the composite have a rutile crystal structure with abundant surface states. The variation in resonance features of the XANES strongly supports that the crystalline SnO2 NPs interact with CNTs through synergic bonding involving charge redistribution between C 2p-derived states and the valence and conduction bands in SnO2 NPs via interaction at the interface facilitated by oxidation treatment of the CNT prior to composite formation. Raman and ultraviolet photoelectron spectroscopy (UPS) results support the synergic bonding interaction. Such interaction is expected not only to immobilize SnO2 NPs on CNT but also to improve the conductivity of SnO2 NPs.

AB - The interaction between SnO2 and substrate in SnO2 nanoparieles (NPs) - carbon nanotubes (CNTs) composite has been studied by X-ray absorption near-edge structures (XANES) at Sn M5,4, O K-edge and C K-edge. SnO2 NPs in the composite have a rutile crystal structure with abundant surface states. The variation in resonance features of the XANES strongly supports that the crystalline SnO2 NPs interact with CNTs through synergic bonding involving charge redistribution between C 2p-derived states and the valence and conduction bands in SnO2 NPs via interaction at the interface facilitated by oxidation treatment of the CNT prior to composite formation. Raman and ultraviolet photoelectron spectroscopy (UPS) results support the synergic bonding interaction. Such interaction is expected not only to immobilize SnO2 NPs on CNT but also to improve the conductivity of SnO2 NPs.

UR - https://www.scopus.com/pages/publications/65249143981

U2 - 10.1021/jp810639y

DO - 10.1021/jp810639y

M3 - 文章

AN - SCOPUS:65249143981

SN - 1932-7447

VL - 113

SP - 6114

EP - 6117

JO - Journal of Physical Chemistry C

JF - Journal of Physical Chemistry C

IS - 15

ER -

An X-ray absorption, photoemission, and raman study of the interaction between SnO₂ nanoparticle and carbon nanotube

Abstract

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