An overview of in situ remediation for groundwater co-contaminated with heavy metals and petroleum hydrocarbons

Groundwater is an important component of water resources. Mixed pollutants comprising heavy metals (HMs) and petroleum hydrocarbons (PHs) from industrial activities can contaminate groundwater through such processes as rainfall infiltration, runoff and discharge, which pose direct threats to human health through the food chain or drinking water. In situ remediation of contaminated groundwater is an important way to improve the quality of a water environment, develop water resources and ensure the safety of drinking water. Bioremediation and permeable reactive barriers (PRBs) were discussed in this paper as they were effective and affordable for in situ remediation of complex contaminated groundwater. In addition, media types, technology combinations and factors for the PRBs were highlighted. Finally, insights and outlooks were presented for in situ remediation technologies for complex groundwater contaminated with HMs and PHs. The selection of an in situ remediation technology should be site specific. The remediation of complex contaminated groundwater can be approached from various perspectives, including the development of economical materials, the production of slow-release and encapsulated materials, and a combination of multiple technologies. This review is expected to provide technical guidance and assistance for in situ remediation of complex contaminated groundwater.