Adsorption of Cr(VI) by Nanosized Rutile under the Action of UV Radiation

N. V. Pechishcheva; D. P. Ordinartsev; A. A. Valeeva; P. V. Zaitseva; A. D. Korobitsyna; A. A. Sushnikova; A. V. Kim; K. Yu Shunyaev; A. A. Rempel’

doi:10.1134/S0036024423020206

Adsorption of Cr(VI) by Nanosized Rutile under the Action of UV Radiation

N. V. Pechishcheva^*
, D. P. Ordinartsev
, A. A. Valeeva
, P. V. Zaitseva
, A. D. Korobitsyna
, A. A. Sushnikova
, A. V. Kim
, K. Yu Shunyaev
, A. A. Rempel’

^*Corresponding author for this work

Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences
Institute of Solid State Chemistry of the Ural Branch of the Russian Academy of Sciences
Ural Federal University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Abstract: the properties of nanosized sorbents prepared by high-energy milling from microcrystalline powder of titanium dioxide of rutile modification have been studied. It was established that milling to an average crystallite size of ~30 nm and ultraviolet illumination significantly improved the sorption properties of rutile with respect to chromium compared with those of the starting material and the ability of Cr(VI) to be reduced to Cr(III) in its presence. The maximum removal of Cr(VI) from aqueous solutions with a concentration of 50 mg/L was achieved under UV illumination in an acetate buffer medium at pH 4–5 and a content of ground rutile of 16.7 g/L. A mechanism of adsorption was proposed.

Original language	English
Pages (from-to)	392-396
Number of pages	5
Journal	Russian Journal of Physical Chemistry A
Volume	97
Issue number	2
DOIs	https://doi.org/10.1134/S0036024423020206
State	Published - Feb 2023
Externally published	Yes

Keywords

adsorption
chromium(VI)
rutile
ultraviolet

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10.1134/S0036024423020206

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@article{3ad49ab520a24373819863a2da29ea85,

title = "Adsorption of Cr(VI) by Nanosized Rutile under the Action of UV Radiation",

abstract = "Abstract: the properties of nanosized sorbents prepared by high-energy milling from microcrystalline powder of titanium dioxide of rutile modification have been studied. It was established that milling to an average crystallite size of \textasciitilde{}30 nm and ultraviolet illumination significantly improved the sorption properties of rutile with respect to chromium compared with those of the starting material and the ability of Cr(VI) to be reduced to Cr(III) in its presence. The maximum removal of Cr(VI) from aqueous solutions with a concentration of 50 mg/L was achieved under UV illumination in an acetate buffer medium at pH 4–5 and a content of ground rutile of 16.7 g/L. A mechanism of adsorption was proposed.",

keywords = "adsorption, chromium(VI), rutile, ultraviolet",

author = "Pechishcheva, \{N. V.\} and Ordinartsev, \{D. P.\} and Valeeva, \{A. A.\} and Zaitseva, \{P. V.\} and Korobitsyna, \{A. D.\} and Sushnikova, \{A. A.\} and Kim, \{A. V.\} and Shunyaev, \{K. Yu\} and Rempel{\textquoteright}, \{A. A.\}",

note = "Publisher Copyright: {\textcopyright} 2023, Pleiades Publishing, Ltd.",

year = "2023",

month = feb,

doi = "10.1134/S0036024423020206",

language = "英语",

volume = "97",

pages = "392--396",

journal = "Russian Journal of Physical Chemistry A",

issn = "0036-0244",

publisher = "Pleiades Publishing",

number = "2",

}

TY - JOUR

T1 - Adsorption of Cr(VI) by Nanosized Rutile under the Action of UV Radiation

AU - Pechishcheva, N. V.

AU - Ordinartsev, D. P.

AU - Valeeva, A. A.

AU - Zaitseva, P. V.

AU - Korobitsyna, A. D.

AU - Sushnikova, A. A.

AU - Kim, A. V.

AU - Shunyaev, K. Yu

AU - Rempel’, A. A.

PY - 2023/2

Y1 - 2023/2

N2 - Abstract: the properties of nanosized sorbents prepared by high-energy milling from microcrystalline powder of titanium dioxide of rutile modification have been studied. It was established that milling to an average crystallite size of ~30 nm and ultraviolet illumination significantly improved the sorption properties of rutile with respect to chromium compared with those of the starting material and the ability of Cr(VI) to be reduced to Cr(III) in its presence. The maximum removal of Cr(VI) from aqueous solutions with a concentration of 50 mg/L was achieved under UV illumination in an acetate buffer medium at pH 4–5 and a content of ground rutile of 16.7 g/L. A mechanism of adsorption was proposed.

AB - Abstract: the properties of nanosized sorbents prepared by high-energy milling from microcrystalline powder of titanium dioxide of rutile modification have been studied. It was established that milling to an average crystallite size of ~30 nm and ultraviolet illumination significantly improved the sorption properties of rutile with respect to chromium compared with those of the starting material and the ability of Cr(VI) to be reduced to Cr(III) in its presence. The maximum removal of Cr(VI) from aqueous solutions with a concentration of 50 mg/L was achieved under UV illumination in an acetate buffer medium at pH 4–5 and a content of ground rutile of 16.7 g/L. A mechanism of adsorption was proposed.

KW - adsorption

KW - chromium(VI)

KW - rutile

KW - ultraviolet

UR - https://www.scopus.com/pages/publications/85156117175

U2 - 10.1134/S0036024423020206

DO - 10.1134/S0036024423020206

M3 - 文章

AN - SCOPUS:85156117175

SN - 0036-0244

VL - 97

SP - 392

EP - 396

JO - Russian Journal of Physical Chemistry A

JF - Russian Journal of Physical Chemistry A

IS - 2

ER -

Adsorption of Cr(VI) by Nanosized Rutile under the Action of UV Radiation

Abstract

Keywords

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