A three volt lithium ion battery with LiCoPO4 and zero-strain Li4Ti5O12 as insertion material

Chenqiang Du; Zhiyuan Tang; Junwei Wu; Haoqing Tang; Xinhe Zhang

doi:10.1016/j.electacta.2014.01.093

A three volt lithium ion battery with LiCoPO₄ and zero-strain Li₄Ti₅O₁₂ as insertion material

Chenqiang Du^*
, Zhiyuan Tang
, Junwei Wu
, Haoqing Tang
, Xinhe Zhang

^*Corresponding author for this work

Tianjin University
Harbin Institute of Technology Shenzhen
McNair Technology Co., Ltd.

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

A 3 V lithium ion battery with LiCoPO₄ and zero-strain Li ₄Ti₅O₁₂ as insertion material is constructed and investigated. Electrochemical tests show that the full cell displays two operation voltage plateaus (3.24 V and 3.17 V). Further, the effects of the theoretical capacity matchup ratio between cathode and anode in the LiCoPO ₄/Li₄Ti₅O₁₂ cell system on the electrochemical properties are firstly investigated. The LiCoPO ₄/Li₄Ti₅O₁₂ cell delivers a highest initial discharge capacity of 135.6 mAh g^-1. A 3.2 V lithium-ion battery would further extend the application of lithium ion batteries in energy conversion and storage applications.

Original language	English
Pages (from-to)	58-64
Number of pages	7
Journal	Electrochimica Acta
Volume	125
DOIs	https://doi.org/10.1016/j.electacta.2014.01.093
State	Published - 10 Apr 2014
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

capacity matchup
lithium cobalt phosphate
lithium ion battery
lithium titanate oxide

Access to Document

10.1016/j.electacta.2014.01.093

Cite this

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title = "A three volt lithium ion battery with LiCoPO4 and zero-strain Li4Ti5O12 as insertion material",

abstract = "A 3 V lithium ion battery with LiCoPO4 and zero-strain Li 4Ti5O12 as insertion material is constructed and investigated. Electrochemical tests show that the full cell displays two operation voltage plateaus (3.24 V and 3.17 V). Further, the effects of the theoretical capacity matchup ratio between cathode and anode in the LiCoPO 4/Li4Ti5O12 cell system on the electrochemical properties are firstly investigated. The LiCoPO 4/Li4Ti5O12 cell delivers a highest initial discharge capacity of 135.6 mAh g-1. A 3.2 V lithium-ion battery would further extend the application of lithium ion batteries in energy conversion and storage applications.",

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author = "Chenqiang Du and Zhiyuan Tang and Junwei Wu and Haoqing Tang and Xinhe Zhang",

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AU - Du, Chenqiang

AU - Tang, Zhiyuan

AU - Wu, Junwei

AU - Tang, Haoqing

AU - Zhang, Xinhe

PY - 2014/4/10

Y1 - 2014/4/10

N2 - A 3 V lithium ion battery with LiCoPO4 and zero-strain Li 4Ti5O12 as insertion material is constructed and investigated. Electrochemical tests show that the full cell displays two operation voltage plateaus (3.24 V and 3.17 V). Further, the effects of the theoretical capacity matchup ratio between cathode and anode in the LiCoPO 4/Li4Ti5O12 cell system on the electrochemical properties are firstly investigated. The LiCoPO 4/Li4Ti5O12 cell delivers a highest initial discharge capacity of 135.6 mAh g-1. A 3.2 V lithium-ion battery would further extend the application of lithium ion batteries in energy conversion and storage applications.

AB - A 3 V lithium ion battery with LiCoPO4 and zero-strain Li 4Ti5O12 as insertion material is constructed and investigated. Electrochemical tests show that the full cell displays two operation voltage plateaus (3.24 V and 3.17 V). Further, the effects of the theoretical capacity matchup ratio between cathode and anode in the LiCoPO 4/Li4Ti5O12 cell system on the electrochemical properties are firstly investigated. The LiCoPO 4/Li4Ti5O12 cell delivers a highest initial discharge capacity of 135.6 mAh g-1. A 3.2 V lithium-ion battery would further extend the application of lithium ion batteries in energy conversion and storage applications.

KW - capacity matchup

KW - lithium cobalt phosphate

KW - lithium ion battery

KW - lithium titanate oxide

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