A supra-cubane-like Mo/S/Cu cluster: Cation-directed synthesis, crystal structure and nonlinear optical property

Jinfang Zhang; Weitao Chen; Yu Fang; Ding Jia; Yinlin Wang; Yinglin Song; Chi Zhang

doi:10.1016/j.poly.2015.07.044

A supra-cubane-like Mo/S/Cu cluster: Cation-directed synthesis, crystal structure and nonlinear optical property

Jinfang Zhang^*
, Weitao Chen
, Yu Fang
, Ding Jia
, Yinlin Wang
, Yinglin Song
, Chi Zhang

^*Corresponding author for this work

Jiangnan University
Jiangsu University
Soochow University

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Abstract Directed by potassium-crownether host-guest cation, a unique octameric eicosanuclear heterothiometallic Mo/S/Cu cluster [K(dibenzo-18-crown-6)(DMF)₂]₄[Mo₈S₃₂Cu₁₂] (1) was synthesized by the reaction of (NH₄)₂MoS₄, CuI, KI, dibenzo-18-crown-6 in DMF solution. 1 was characterized by elemental analysis, IR, thermogravimetric analysis, X-ray powder and single crystal diffractions. 1 crystallizes in the tetragonal space group I4₁cd. The anionic octameric eicosanuclear [Mo₈S₃₂Cu₁₂]^4- cluster exhibits a supra-cubane-like skeleton, fabricated by four nest-shaped clusters [Mo(μ₁-S)(μ₃-S)₃Cu₃]⁺ and four flywheel-shaped clusters [Mo(μ₂-S)₃(μ₄-S)Cu₃]⁺ linking together through shared Cu atoms. The cation [K(dibenzo-18-crown-6)(DMF)₂]⁺ of 1 exhibits the host-guest configuration, where K⁺ is embedded in the center of dibenzo-18-crown-6. Furthermore, Z-scan studies (532 nm, 21 ps pulses) reveal that 1 possesses effective third-order nonlinear optical (NLO) properties.

Original language	English
Article number	11430
Pages (from-to)	1-5
Number of pages	5
Journal	Polyhedron
Volume	101
DOIs	https://doi.org/10.1016/j.poly.2015.07.044
State	Published - 5 Aug 2015
Externally published	Yes

Keywords

Crystal structure
Heterothiometallic Mo/S/Cu cluster
Host-guest cation-directed synthesis
Nonlinear optical property
Supra-cubane-like skeleton

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@article{4b63a1f0ba284139932dc014cdf6a861,

title = "A supra-cubane-like Mo/S/Cu cluster: Cation-directed synthesis, crystal structure and nonlinear optical property",

abstract = "Abstract Directed by potassium-crownether host-guest cation, a unique octameric eicosanuclear heterothiometallic Mo/S/Cu cluster [K(dibenzo-18-crown-6)(DMF)2]4[Mo8S32Cu12] (1) was synthesized by the reaction of (NH4)2MoS4, CuI, KI, dibenzo-18-crown-6 in DMF solution. 1 was characterized by elemental analysis, IR, thermogravimetric analysis, X-ray powder and single crystal diffractions. 1 crystallizes in the tetragonal space group I41cd. The anionic octameric eicosanuclear [Mo8S32Cu12]4- cluster exhibits a supra-cubane-like skeleton, fabricated by four nest-shaped clusters [Mo(μ1-S)(μ3-S)3Cu3]+ and four flywheel-shaped clusters [Mo(μ2-S)3(μ4-S)Cu3]+ linking together through shared Cu atoms. The cation [K(dibenzo-18-crown-6)(DMF)2]+ of 1 exhibits the host-guest configuration, where K+ is embedded in the center of dibenzo-18-crown-6. Furthermore, Z-scan studies (532 nm, 21 ps pulses) reveal that 1 possesses effective third-order nonlinear optical (NLO) properties.",

keywords = "Crystal structure, Heterothiometallic Mo/S/Cu cluster, Host-guest cation-directed synthesis, Nonlinear optical property, Supra-cubane-like skeleton",

author = "Jinfang Zhang and Weitao Chen and Yu Fang and Ding Jia and Yinlin Wang and Yinglin Song and Chi Zhang",

note = "Publisher Copyright: {\textcopyright} 2015 Elsevier Ltd.",

year = "2015",

month = aug,

day = "5",

doi = "10.1016/j.poly.2015.07.044",

language = "英语",

volume = "101",

pages = "1--5",

journal = "Polyhedron",

issn = "0277-5387",

publisher = "Elsevier Ltd",

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TY - JOUR

T1 - A supra-cubane-like Mo/S/Cu cluster

T2 - Cation-directed synthesis, crystal structure and nonlinear optical property

AU - Zhang, Jinfang

AU - Chen, Weitao

AU - Fang, Yu

AU - Jia, Ding

AU - Wang, Yinlin

AU - Song, Yinglin

AU - Zhang, Chi

PY - 2015/8/5

Y1 - 2015/8/5

N2 - Abstract Directed by potassium-crownether host-guest cation, a unique octameric eicosanuclear heterothiometallic Mo/S/Cu cluster [K(dibenzo-18-crown-6)(DMF)2]4[Mo8S32Cu12] (1) was synthesized by the reaction of (NH4)2MoS4, CuI, KI, dibenzo-18-crown-6 in DMF solution. 1 was characterized by elemental analysis, IR, thermogravimetric analysis, X-ray powder and single crystal diffractions. 1 crystallizes in the tetragonal space group I41cd. The anionic octameric eicosanuclear [Mo8S32Cu12]4- cluster exhibits a supra-cubane-like skeleton, fabricated by four nest-shaped clusters [Mo(μ1-S)(μ3-S)3Cu3]+ and four flywheel-shaped clusters [Mo(μ2-S)3(μ4-S)Cu3]+ linking together through shared Cu atoms. The cation [K(dibenzo-18-crown-6)(DMF)2]+ of 1 exhibits the host-guest configuration, where K+ is embedded in the center of dibenzo-18-crown-6. Furthermore, Z-scan studies (532 nm, 21 ps pulses) reveal that 1 possesses effective third-order nonlinear optical (NLO) properties.

AB - Abstract Directed by potassium-crownether host-guest cation, a unique octameric eicosanuclear heterothiometallic Mo/S/Cu cluster [K(dibenzo-18-crown-6)(DMF)2]4[Mo8S32Cu12] (1) was synthesized by the reaction of (NH4)2MoS4, CuI, KI, dibenzo-18-crown-6 in DMF solution. 1 was characterized by elemental analysis, IR, thermogravimetric analysis, X-ray powder and single crystal diffractions. 1 crystallizes in the tetragonal space group I41cd. The anionic octameric eicosanuclear [Mo8S32Cu12]4- cluster exhibits a supra-cubane-like skeleton, fabricated by four nest-shaped clusters [Mo(μ1-S)(μ3-S)3Cu3]+ and four flywheel-shaped clusters [Mo(μ2-S)3(μ4-S)Cu3]+ linking together through shared Cu atoms. The cation [K(dibenzo-18-crown-6)(DMF)2]+ of 1 exhibits the host-guest configuration, where K+ is embedded in the center of dibenzo-18-crown-6. Furthermore, Z-scan studies (532 nm, 21 ps pulses) reveal that 1 possesses effective third-order nonlinear optical (NLO) properties.

KW - Crystal structure

KW - Heterothiometallic Mo/S/Cu cluster

KW - Host-guest cation-directed synthesis

KW - Nonlinear optical property

KW - Supra-cubane-like skeleton

UR - https://www.scopus.com/pages/publications/84938582739

U2 - 10.1016/j.poly.2015.07.044

DO - 10.1016/j.poly.2015.07.044

M3 - 文章

AN - SCOPUS:84938582739

SN - 0277-5387

VL - 101

SP - 1

EP - 5

JO - Polyhedron

JF - Polyhedron

M1 - 11430

ER -

A supra-cubane-like Mo/S/Cu cluster: Cation-directed synthesis, crystal structure and nonlinear optical property

Abstract

Keywords

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