A super thin polytetrafluoroethylene/sulfonated poly(ether ether ketone) membrane with 91% energy efficiency and high stability for vanadium redox flow battery

Jicui Dai; Xiangguo Teng; Yiqiao Song; Xiaomei Jiang; Geping Yin

doi:10.1002/app.43593

A super thin polytetrafluoroethylene/sulfonated poly(ether ether ketone) membrane with 91% energy efficiency and high stability for vanadium redox flow battery

Jicui Dai
, Xiangguo Teng^*
, Yiqiao Song
, Xiaomei Jiang
, Geping Yin

^*Corresponding author for this work

School of Marine Science and Technology, Harbin Institute of Technology Weihai
School of Chemistry and Chemical Engineering, Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

20 Scopus citations

Abstract

In order to further decrease the cost and enhance the durability of sulfonated poly(ether ether ketone) membrane for vanadium redox flow battery, a super thin (40 μm) polytetrafluoroethylene (PTFE)/SPEEK (PS) membrane is prepared. The physico-chemical properties and single cell performance of PS membranes prepared with different casting solvents including NMP (N-methyl-2-pyrrolidone), DMF (N,N′-dimethylformamide), and DMAc (N,N′-dimethylacetamide) have been investigated. Results show that the energy efficiency of VRB with PS/DMF can reach up to 91.2% at the current density of 40 mA cm^-2, which is 11.1% and 6.4% higher than that of the commercial Nafion 212 and pristine SPEEK membrane, respectively. In addition, charge-discharge test over 150 times proves that the PS/DMF membrane possesses high stability and thus it is suitable for VRB application.

Original language	English
Article number	43593
Journal	Journal of Applied Polymer Science
Volume	133
Issue number	26
DOIs	https://doi.org/10.1002/app.43593
State	Published - 10 Jul 2016
Externally published	Yes

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

polytetrafluoroethylene
sulfonated poly(ether ether ketone)
vanadium redox flow battery

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10.1002/app.43593

Cite this

@article{0b584c604d23476bb518c64497dfbcf7,

title = "A super thin polytetrafluoroethylene/sulfonated poly(ether ether ketone) membrane with 91\% energy efficiency and high stability for vanadium redox flow battery",

abstract = "In order to further decrease the cost and enhance the durability of sulfonated poly(ether ether ketone) membrane for vanadium redox flow battery, a super thin (40 μm) polytetrafluoroethylene (PTFE)/SPEEK (PS) membrane is prepared. The physico-chemical properties and single cell performance of PS membranes prepared with different casting solvents including NMP (N-methyl-2-pyrrolidone), DMF (N,N′-dimethylformamide), and DMAc (N,N′-dimethylacetamide) have been investigated. Results show that the energy efficiency of VRB with PS/DMF can reach up to 91.2\% at the current density of 40 mA cm-2, which is 11.1\% and 6.4\% higher than that of the commercial Nafion 212 and pristine SPEEK membrane, respectively. In addition, charge-discharge test over 150 times proves that the PS/DMF membrane possesses high stability and thus it is suitable for VRB application.",

keywords = "polytetrafluoroethylene, sulfonated poly(ether ether ketone), vanadium redox flow battery",

author = "Jicui Dai and Xiangguo Teng and Yiqiao Song and Xiaomei Jiang and Geping Yin",

note = "Publisher Copyright: {\textcopyright} 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43593.",

year = "2016",

month = jul,

day = "10",

doi = "10.1002/app.43593",

language = "英语",

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T1 - A super thin polytetrafluoroethylene/sulfonated poly(ether ether ketone) membrane with 91% energy efficiency and high stability for vanadium redox flow battery

AU - Dai, Jicui

AU - Teng, Xiangguo

AU - Song, Yiqiao

AU - Jiang, Xiaomei

AU - Yin, Geping

PY - 2016/7/10

Y1 - 2016/7/10

N2 - In order to further decrease the cost and enhance the durability of sulfonated poly(ether ether ketone) membrane for vanadium redox flow battery, a super thin (40 μm) polytetrafluoroethylene (PTFE)/SPEEK (PS) membrane is prepared. The physico-chemical properties and single cell performance of PS membranes prepared with different casting solvents including NMP (N-methyl-2-pyrrolidone), DMF (N,N′-dimethylformamide), and DMAc (N,N′-dimethylacetamide) have been investigated. Results show that the energy efficiency of VRB with PS/DMF can reach up to 91.2% at the current density of 40 mA cm-2, which is 11.1% and 6.4% higher than that of the commercial Nafion 212 and pristine SPEEK membrane, respectively. In addition, charge-discharge test over 150 times proves that the PS/DMF membrane possesses high stability and thus it is suitable for VRB application.

AB - In order to further decrease the cost and enhance the durability of sulfonated poly(ether ether ketone) membrane for vanadium redox flow battery, a super thin (40 μm) polytetrafluoroethylene (PTFE)/SPEEK (PS) membrane is prepared. The physico-chemical properties and single cell performance of PS membranes prepared with different casting solvents including NMP (N-methyl-2-pyrrolidone), DMF (N,N′-dimethylformamide), and DMAc (N,N′-dimethylacetamide) have been investigated. Results show that the energy efficiency of VRB with PS/DMF can reach up to 91.2% at the current density of 40 mA cm-2, which is 11.1% and 6.4% higher than that of the commercial Nafion 212 and pristine SPEEK membrane, respectively. In addition, charge-discharge test over 150 times proves that the PS/DMF membrane possesses high stability and thus it is suitable for VRB application.

KW - polytetrafluoroethylene

KW - sulfonated poly(ether ether ketone)

KW - vanadium redox flow battery

UR - https://www.scopus.com/pages/publications/84978012485

U2 - 10.1002/app.43593

DO - 10.1002/app.43593

M3 - 文章

AN - SCOPUS:84978012485

SN - 0021-8995

VL - 133

JO - Journal of Applied Polymer Science

JF - Journal of Applied Polymer Science

IS - 26

M1 - 43593

ER -

A super thin polytetrafluoroethylene/sulfonated poly(ether ether ketone) membrane with 91% energy efficiency and high stability for vanadium redox flow battery

Abstract

UN SDGs

Keywords

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