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A Stereoseiective Reductive Rearrangement of Allylic Epoxyalcohols - New Synthetic Method of 1,3-Diol

  • Yong Qiang Tu*
  • , Wu Jiong Xia
  • , Ping Zhen Wang
  • , Jian Jun Zhai
  • , Yao Zu Chen
  • *Corresponding author for this work
  • Lanzhou University

Research output: Contribution to journalArticlepeer-review

Abstract

A novel method for synthesis of stereoselective 1,3-diol from α-hydroxyepoxides was developed by reductive rearrangement with aluminum isopropoxide, which is very convenient and efficient. The substituted effect and stereochemistry were also discussed.

Original languageEnglish
Pages (from-to)589
Number of pages1
JournalGaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume20
Issue number4
StatePublished - 1999
Externally publishedYes

Keywords

  • Epoxyalcohols
  • Rearrangement
  • Stereoselective

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