A simple method for preparing 2, 6-diamino-3, 5-dinitropyridine-1-oxide

Yanhong Wang; Yuanjun Song; Zhen Hu; Jiehui Jing; Xiangli Meng; Yudong Huang

A simple method for preparing 2, 6-diamino-3, 5-dinitropyridine-1-oxide

Yanhong Wang^*
, Yuanjun Song
, Zhen Hu
, Jiehui Jing
, Xiangli Meng
, Yudong Huang

^*Corresponding author for this work

School of Chemistry and Chemical Engineering

Harbin Institute of Technology

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

A simple synthetic method of 2, 6-diamino-3, 5-dinitropyridine-l-oxide (DADNP-1-O) was described. DADNP-1-0 was synthesized using 2, 6-diaminopyridine as a starting material in three steps including acidification, nitration and N-oxidation with a total yield of above 90%. The structures of intermediates and DADNP-1-0 were determined by IR, ¹H NMR, ¹³C NMR, HPLC, DSC and elemental analysis.

Original language	English
Pages (from-to)	780-783
Number of pages	4
Journal	Chinese Journal of Organic Chemistry
Volume	29
Issue number	5
State	Published - May 2009

Keywords

2, 6-diamino-3
5-dinitropyridine-l-oxide
Energetic material
N-oxidation
Nitration
Synthesis

Cite this

@article{1e8409d0368c41179199afcc3a88e12d,

title = "A simple method for preparing 2, 6-diamino-3, 5-dinitropyridine-1-oxide",

abstract = "A simple synthetic method of 2, 6-diamino-3, 5-dinitropyridine-l-oxide (DADNP-1-O) was described. DADNP-1-0 was synthesized using 2, 6-diaminopyridine as a starting material in three steps including acidification, nitration and N-oxidation with a total yield of above 90\%. The structures of intermediates and DADNP-1-0 were determined by IR, 1H NMR, 13C NMR, HPLC, DSC and elemental analysis.",

keywords = "2, 6-diamino-3, 5-dinitropyridine-l-oxide, Energetic material, N-oxidation, Nitration, Synthesis",

author = "Yanhong Wang and Yuanjun Song and Zhen Hu and Jiehui Jing and Xiangli Meng and Yudong Huang",

year = "2009",

month = may,

language = "英语",

volume = "29",

pages = "780--783",

journal = "Chinese Journal of Organic Chemistry",

issn = "0253-2786",

publisher = "Science Press ",

number = "5",

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TY - JOUR

T1 - A simple method for preparing 2, 6-diamino-3, 5-dinitropyridine-1-oxide

AU - Wang, Yanhong

AU - Song, Yuanjun

AU - Hu, Zhen

AU - Jing, Jiehui

AU - Meng, Xiangli

AU - Huang, Yudong

PY - 2009/5

Y1 - 2009/5

N2 - A simple synthetic method of 2, 6-diamino-3, 5-dinitropyridine-l-oxide (DADNP-1-O) was described. DADNP-1-0 was synthesized using 2, 6-diaminopyridine as a starting material in three steps including acidification, nitration and N-oxidation with a total yield of above 90%. The structures of intermediates and DADNP-1-0 were determined by IR, 1H NMR, 13C NMR, HPLC, DSC and elemental analysis.

AB - A simple synthetic method of 2, 6-diamino-3, 5-dinitropyridine-l-oxide (DADNP-1-O) was described. DADNP-1-0 was synthesized using 2, 6-diaminopyridine as a starting material in three steps including acidification, nitration and N-oxidation with a total yield of above 90%. The structures of intermediates and DADNP-1-0 were determined by IR, 1H NMR, 13C NMR, HPLC, DSC and elemental analysis.

KW - 2, 6-diamino-3

KW - 5-dinitropyridine-l-oxide

KW - Energetic material

KW - N-oxidation

KW - Nitration

KW - Synthesis

UR - https://www.scopus.com/pages/publications/68949086691

M3 - 文章

AN - SCOPUS:68949086691

SN - 0253-2786

VL - 29

SP - 780

EP - 783

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 5

ER -

A simple method for preparing 2, 6-diamino-3, 5-dinitropyridine-1-oxide

Abstract

Keywords

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